Mass transfer in mesoporous materials: the benefit of microscopic diffusion measurement
J Kärger, R Valiullin - Chemical Society Reviews, 2013 - pubs.rsc.org
We introduce the various options of experimentally observing mass transfer in mesoporous
materials. It shall be demonstrated that the exploration of the underlying mechanisms is …
materials. It shall be demonstrated that the exploration of the underlying mechanisms is …
Surface barriers to mass transfer in nanoporous materials for catalysis and separations
Surface barriers to mass transfer in various nanoporous materials have been increasingly
identified. These past few years especially, a significant impact on catalysis and separations …
identified. These past few years especially, a significant impact on catalysis and separations …
Diffusion in nanoporous materials: fundamental principles, insights and challenges
J Kärger, DM Ruthven - New Journal of Chemistry, 2016 - pubs.rsc.org
Following a brief review of Fick's laws and the theory of diffusion in a homogeneous
medium, we consider the application of the Fickian model to diffusion in nanoporous …
medium, we consider the application of the Fickian model to diffusion in nanoporous …
Pulsed field gradient NMR diffusion measurement in nanoporous materials
Labeling in diffusion measurements by pulsed field gradient (PFG) NMR is based on the
observation of the phase of nuclear spins acquired in a constant magnetic field with …
observation of the phase of nuclear spins acquired in a constant magnetic field with …
Structural analysis of hierarchically organized zeolites
Advances in materials synthesis bring about many opportunities for technological
applications, but are often accompanied by unprecedented complexity. This is clearly …
applications, but are often accompanied by unprecedented complexity. This is clearly …
The role of mesopores in intracrystalline transport in USY zeolite: PFG NMR diffusion study on various length scales
PFG NMR has been applied to study intracrystalline diffusion in USY zeolite as well as in the
parent ammonium-ion exchanged zeolite Y used to produce the USY by zeolite steaming …
parent ammonium-ion exchanged zeolite Y used to produce the USY by zeolite steaming …
Understanding the Role of Internal Diffusion Barriers in Pt/Beta Zeolite Catalyzed Isomerization of n‐Heptane
Applications of zeolites in catalysis are plagued by strong diffusion resistance, which results
from limitations to molecular transport in micropores, across external crystal surfaces, but …
from limitations to molecular transport in micropores, across external crystal surfaces, but …
[HTML][HTML] Effects of zeolite particle size and internal grain boundaries on Pt/Beta catalyzed isomerization of n-pentane
The impact of particle size and internal grain boundaries of Beta zeolites was investigated in
n-pentane isomerization over bifunctional Pt/Beta catalysts, by comparing the catalytic …
n-pentane isomerization over bifunctional Pt/Beta catalysts, by comparing the catalytic …
Transport phenomena in nanoporous materials
J Kärger - ChemPhysChem, 2015 - Wiley Online Library
Diffusion, that is, the irregular movement of atoms and molecules, is a universal
phenomenon of mass transfer occurring in all states of matter. It is of equal importance for …
phenomenon of mass transfer occurring in all states of matter. It is of equal importance for …
Fundamentals of adsorption equilibrium and kinetics in microporous solids
DM Ruthven - Adsorption and Diffusion, 2006 - Springer
This chapter is intended to provide a general introduction to the basic principles of
adsorption equilibrium and kinetics, which is the focus of the present volume. The discussion …
adsorption equilibrium and kinetics, which is the focus of the present volume. The discussion …