Mass transfer in mesoporous materials: the benefit of microscopic diffusion measurement

J Kärger, R Valiullin - Chemical Society Reviews, 2013 - pubs.rsc.org
We introduce the various options of experimentally observing mass transfer in mesoporous
materials. It shall be demonstrated that the exploration of the underlying mechanisms is …

Surface barriers to mass transfer in nanoporous materials for catalysis and separations

S Xu, K Zheng, CR Boruntea, D Cheng… - Chemical Society …, 2023 - pubs.rsc.org
Surface barriers to mass transfer in various nanoporous materials have been increasingly
identified. These past few years especially, a significant impact on catalysis and separations …

Diffusion in nanoporous materials: fundamental principles, insights and challenges

J Kärger, DM Ruthven - New Journal of Chemistry, 2016 - pubs.rsc.org
Following a brief review of Fick's laws and the theory of diffusion in a homogeneous
medium, we consider the application of the Fickian model to diffusion in nanoporous …

Pulsed field gradient NMR diffusion measurement in nanoporous materials

J Kärger, M Avramovska, D Freude, J Haase, S Hwang… - Adsorption, 2021 - Springer
Labeling in diffusion measurements by pulsed field gradient (PFG) NMR is based on the
observation of the phase of nuclear spins acquired in a constant magnetic field with …

Structural analysis of hierarchically organized zeolites

S Mitchell, AB Pinar, J Kenvin, P Crivelli… - Nature …, 2015 - nature.com
Advances in materials synthesis bring about many opportunities for technological
applications, but are often accompanied by unprecedented complexity. This is clearly …

The role of mesopores in intracrystalline transport in USY zeolite: PFG NMR diffusion study on various length scales

P Kortunov, S Vasenkov, J Kärger… - Journal of the …, 2005 - ACS Publications
PFG NMR has been applied to study intracrystalline diffusion in USY zeolite as well as in the
parent ammonium-ion exchanged zeolite Y used to produce the USY by zeolite steaming …

Understanding the Role of Internal Diffusion Barriers in Pt/Beta Zeolite Catalyzed Isomerization of n‐Heptane

Z Guo, X Li, S Hu, G Ye, X Zhou… - Angewandte …, 2020 - Wiley Online Library
Applications of zeolites in catalysis are plagued by strong diffusion resistance, which results
from limitations to molecular transport in micropores, across external crystal surfaces, but …

[HTML][HTML] Effects of zeolite particle size and internal grain boundaries on Pt/Beta catalyzed isomerization of n-pentane

G Ye, Y Sun, Z Guo, K Zhu, H Liu, X Zhou… - Journal of …, 2018 - Elsevier
The impact of particle size and internal grain boundaries of Beta zeolites was investigated in
n-pentane isomerization over bifunctional Pt/Beta catalysts, by comparing the catalytic …

Transport phenomena in nanoporous materials

J Kärger - ChemPhysChem, 2015 - Wiley Online Library
Diffusion, that is, the irregular movement of atoms and molecules, is a universal
phenomenon of mass transfer occurring in all states of matter. It is of equal importance for …

Fundamentals of adsorption equilibrium and kinetics in microporous solids

DM Ruthven - Adsorption and Diffusion, 2006 - Springer
This chapter is intended to provide a general introduction to the basic principles of
adsorption equilibrium and kinetics, which is the focus of the present volume. The discussion …