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Heterometallic cages: synthesis and applications
High symmetry metallosupramolecular architectures (MSAs) have been exploited for a
range of applications including molecular recognition, catalysis and drug delivery. Recently …
range of applications including molecular recognition, catalysis and drug delivery. Recently …
Molecular barrels as potential hosts: from synthesis to applications
Self-assembled discrete molecular architectures that show selective molecular recognition
within their internal cavities are highly desirable. Such hosts often show guest recognition …
within their internal cavities are highly desirable. Such hosts often show guest recognition …
Self-assembled metallacage with second near-infrared aggregation-induced emission for enhanced multimodal theranostics
The construction of supramolecular coordination complexes (SCCs) featuring prominent
cancer theranostic functions is an appealing yet significantly challenging task. In this study …
cancer theranostic functions is an appealing yet significantly challenging task. In this study …
Recent developments in the preparation and chemistry of metallacycles and metallacages via coordination
The continued development of molecular architectures of consequence to both longstanding
and newly recognized problems demands ever evolving synthetic routes, characterizations …
and newly recognized problems demands ever evolving synthetic routes, characterizations …
The development of ruthenium (II) polypyridyl complexes and conjugates for in vitro cellular and in vivo applications
Ruthenium (II)[Ru (II)] polypyridyl complexes have been the focus of intense investigations
since work began exploring their supramolecular interactions with DNA. In recent years …
since work began exploring their supramolecular interactions with DNA. In recent years …
Terpyridine-based metallosupramolecular constructs: tailored monomers to precise 2D-motifs and 3D-metallocages
This overview represents a comprehensive summary of the recent developments in the
growing field of terpyridine-based, discrete metallosupramolecular architectures. The N …
growing field of terpyridine-based, discrete metallosupramolecular architectures. The N …
Self-Assembled Pd12 Coordination Cage as Photoregulated Oxidase-Like Nanozyme
Designing supramolecular architectures with uncommon geometries embedded with
functional building units is of immense importance in contemporary research. In this report …
functional building units is of immense importance in contemporary research. In this report …
Beyond platonic: how to build metal–organic polyhedra capable of binding low-symmetry, information-rich molecular cargoes
The field of metallosupramolecular chemistry has advanced rapidly in recent years. Much
work in this area has focused on the formation of hollow self-assembled metal-organic …
work in this area has focused on the formation of hollow self-assembled metal-organic …
A Reduced‐Symmetry Heterobimetallic [PdPtL4]4+ Cage: Assembly, Guest Binding, and Stimulus‐Induced Switching
A strategy is presented that enables the quantitative assembly of a heterobimetallic [PdPtL4]
4+ cage. The presence of two different metal ions (PdII and PtII) with differing labilities …
4+ cage. The presence of two different metal ions (PdII and PtII) with differing labilities …
Controlled Formation of Heteroleptic [Pd2(La)2(Lb)2]4+ Cages
Metallosupramolecular architectures are beginning to be exploited for a range of
applications including drug delivery, catalysis, molecular recognition, and sensing. For the …
applications including drug delivery, catalysis, molecular recognition, and sensing. For the …