Asymmetric organocatalytic oxidations have been witnessed to an impressive development
in the last years thanks to the establishment of important chiral hypervalent iodines (III/V) …

Starting from the early 1990s, the chemistry of polyvalent iodine organic compounds has
experienced an explosive development. This surging interest in iodine compounds is mainly …

The fluorination of organic molecules is a rapidly evolving and exciting field in synthesis,
which still poses huge challenges despite the advances made in the past decades …

The impressive development of hypervalent iodine chemistry in recent years is reflected by
the number of publications in this area. Although the synthesis of the first hypervalent iodine …

Hypervalent iodine (III) reagents have been known for over a century, and their reaction
profile is still actively investigated. Recent years have seen impressive improvements in the …

Alcohols and epoxides are arguably ideal electrophiles for the Friedel-Crafts alkylation,
since they are widely available, require no pre-activation, and produce no stoichiometric …

Molecular structures of the most prominent chiral non‐racemic hypervalent iodine (III)
reagents to date have been elucidated for the first time. The formation of a chirally induced …

Advances in hypervalent iodine chemistry have put the field on the precipice of a second
golden age; the first being pioneered in the 1990s. During that period, C–C bond forming …

This review summarizes the chemistry of hypervalent iodine (III) compounds with emphasis
of their synthetic applications. The preparation and reactions of (difluoroiodo) …

An air‐and moisture‐stable fluoroiodane in the presence of AgBF4 is suitable for selective
geminal difluorination of styrenes under mild reaction conditions. One of the C F bonds is …