For traditional metal complexes, intricate chemistry is required to acquire appropriate
ligands for controlling the electron and steric hindrance of metal active centers …

Chloroethenes (CEs) as common organic pollutants in soil could be attenuated via abiotic
and biotic dechlorination. Nonetheless, information on the key catalyzing matter and their …

The carboxamide functional group has a privileged role in organic and biological chemistry
due to its prevalence and utility across synthetic and natural products. Due to nN→ π* CO …

Radical-polar crossover mechanisms are invoked in numerous late transition metal and
photocatalyzed reactions. To the best of our knowledge, reductive radical-polar crossover …

A reagent‐controlled diastereodivergent copper‐catalyzed borylative difunctionalization is
reported. The formation of Lewis adducts that guide selectivity is commonly invoked in …

We describe a catalytic cascade sequence involving directed C (sp3)− H activation followed
by β‐heteroatom elimination to generate a PdII (π‐alkene) intermediate that then undergoes …

Controlling the selectivity of reactions of palladium catalysts with various substrates is
challenging. Herein, a general and unprecedented Pd-catalysed four-component inter …

Herein, we report a new air‐stable phosphine‐free 8‐AQ (8‐aminoquinoline) based Mn (I)
carbonyl complex as the catalyst for the C (α)‐alkylation of oxindoles with alcohols. The Mn …

Cobalt catalysts promote highly enantioselective ring‐opening reactions of 2, 5‐
dihydrofurans using vinylidenes. The products are acyclic organozinc compounds that can …

Limonene undergoes a regioselective Pd (II)-catalyzed C (sp2)–H/C (sp2)–H coupling with
acrylic acid esters and amides, α, β-unsaturated ketones, styrenes, and allyl acetate …