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[HTML][HTML] Harnessing high-energy MLCT excited states for artificial photosynthesis
Important fractions of the energy absorbed in natural and artificial photosynthetic schemes
are dissipated via fast internal conversion processes. In contrast, chromophores that …
are dissipated via fast internal conversion processes. In contrast, chromophores that …
Iron (III) carbene complexes with tunable excited state energies for photoredox and upconversion
Substituting precious elements in luminophores and photocatalysts by abundant first-row
transition metals remains a significant challenge, and iron continues to be particularly …
transition metals remains a significant challenge, and iron continues to be particularly …
Controlling the Photophysical Properties of a Series of Isostructural d6 Complexes Based on Cr0, MnI, and FeII
Development of first-row transition metal complexes with similar luminescence and
photoredox properties as widely used RuII polypyridines is attractive because metals from …
photoredox properties as widely used RuII polypyridines is attractive because metals from …
The photoprotection mechanism in the black–brown pigment eumelanin
The natural black–brown pigment eumelanin protects humans from high-energy UV photons
by absorbing and rapidly dissipating their energy before proteins and DNA are damaged …
by absorbing and rapidly dissipating their energy before proteins and DNA are damaged …
Boosting CO2 photoreduction by π–π-induced preassembly between a Cu(I) sensitizer and a pyrene-appended Co(II) catalyst
The design of a highly efficient system for CO2 photoreduction fully based on earth-
abundant elements presents a challenge, which may be overcome by installing suitable …
abundant elements presents a challenge, which may be overcome by installing suitable …
pysisyphus: Exploring potential energy surfaces in ground and excited states
Predicting the energetics of chemical transformations requires localizing stationary points on
a potential energy surface. While educts and products of a chemical reaction may be known …
a potential energy surface. While educts and products of a chemical reaction may be known …
The chemical effect goes resonant–a full quantum mechanical approach on TERS
Lately, experimental evidence of unexpectedly extremely high spatial resolution of tip-
enhanced Raman scattering (TERS) has been demonstrated. Theoretically, two different …
enhanced Raman scattering (TERS) has been demonstrated. Theoretically, two different …
Excited-state switching in rhenium (I) bipyridyl complexes with donor–donor and donor–acceptor substituents
The optical properties of two Re (CO) 3 (bpy) Cl complexes in which the bpy is substituted
with two donor (triphenylamine, TPA, ReTPA2) as well as both donor (TPA) and acceptor …
with two donor (triphenylamine, TPA, ReTPA2) as well as both donor (TPA) and acceptor …
Push–pull effect–how to effectively control photoinduced intramolecular charge transfer processes in rhenium (i) chromophores with ligands of D–A or D–π–A …
Over the last five decades, diimine rhenium (I) tricarbonyl complexes have been extensively
investigated due to their remarkable and widely tuned photophysical properties. These …
investigated due to their remarkable and widely tuned photophysical properties. These …
Controlling Excited State Localization in Bichromophoric Photosensitizers via the Bridging Group
A series of photosensitizers comprised of both an inorganic and an organic chromophore
are investigated in a joint synthetic, spectroscopic, and theoretical study. This …
are investigated in a joint synthetic, spectroscopic, and theoretical study. This …