Borates: A rich source for optical materials

M Mutailipu, KR Poeppelmeier, S Pan - Chemical Reviews, 2020 - ACS Publications
The primary goal of this review is to present a clear chemical perspective of borates in order
to stimulate and facilitate the discovery of new borate-based optical materials. These …

Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals

C Wu, G Yang, MG Humphrey, C Zhang - Coordination Chemistry Reviews, 2018 - Elsevier
Second-order nonlinear optical (NLO) crystals functioning in the ultraviolet (UV) and deep-
ultraviolet (deep-UV) regions are critically important as frequency conversion materials for …

SrB5O7F3 Functionalized with [B5O9F3]6− Chromophores: Accelerating the Rational Design of Deep‐Ultraviolet Nonlinear Optical Materials

M Mutailipu, M Zhang, B Zhang, L Wang… - Angewandte …, 2018 - Wiley Online Library
Fluorooxoborates, benefiting from the large optical band gap, high anisotropy, and ever‐
greater possibility to form non‐centrosymmetric structures activated by the large polarization …

Deep ultraviolet nonlinear optical materials

TT Tran, H Yu, JM Rondinelli… - Chemistry of …, 2016 - ACS Publications
Deep ultraviolet (absorption edge< 200 nm, band gap> 6.2 eV) nonlinear optical (NLO)
materials are of current interest owing to their technological applications and materials …

A New Deep-Ultraviolet Transparent Orthophosphate LiCs2PO4 with Large Second Harmonic Generation Response

L Li, Y Wang, BH Lei, S Han, Z Yang… - Journal of the …, 2016 - ACS Publications
LiCs2PO4, a new deep-ultraviolet (UV) transparent material, was synthesized by the flux
method. The material contains unusual edge-sharing LiO4-PO4 tetrahedra. It exhibits a very …

Simulated pressure-induced blue-shift of phase-matching region and nonlinear optical mechanism for K3B6O10X (X= Cl, Br)

B Zhang, MH Lee, Z Yang, Q **g, S Pan… - Applied Physics …, 2015 - pubs.aip.org
Birefringence plays a great role in phase matching of the nonlinear optical (NLO) crystals.
Small birefringence restricts various crystals from achieving deep-ultraviolet laser output …

Finding the First Squarates Nonlinear Optical Crystal NaHC4O4·H2O with Strong Second Harmonic Generation and Giant Birefringence

X Zhang, D Cao, D Yang, Y Wang, K Wu… - ACS Materials …, 2022 - ACS Publications
With the development of laser technology, nonlinear optical (NLO) crystals with optimal
performance are urgently required. Finding new NLO-active units is necessary to expand the …

A Series of Rare-Earth Borates K7MRE2B15O30 (M = Zn, Cd, Pb; RE = Sc, Y, Gd, Lu) with Large Second Harmonic Generation Responses

Z **e, M Mutailipu, G He, G Han, Y Wang… - Chemistry of …, 2018 - ACS Publications
A series of new rare-earth borate crystals K7MRE2B15O30 (M= Zn, Cd, Pb; RE= Sc, Y, Gd,
Lu) were synthesized by solid-state reaction method. All of the title compounds crystallize in …

Ba3.75MgB7O14F2.5: A Mixed Alkaline-Earth Metal Borate Fluoride with Short Ultraviolet Cutoff Edge and Large Birefringence

Y Bai, X Wang, H Huang, D Dou, C Chen… - Inorganic …, 2023 - ACS Publications
Fluorine-containing borate crystal materials are particularly attractive due to their rich
structural chemistry and excellent properties for optical applications. In this work, a new …

Deep‐Ultraviolet Nonlinear Optics in a Borate Framework with 21‐Ring Channels

Q Wei, JJ Wang, C He, JW Cheng… - Chemistry–A European …, 2016 - Wiley Online Library
A new borate LiBa3 (OH)[B9O16][B (OH) 4], which combines the uniform porosity of open‐
frameworks with the extraordinary NLO properties of borates, has been obtained under …