Sequence-and stereo-defined macromolecules: properties and emerging functionalities

R Szweda - Progress in Polymer Science, 2023 - Elsevier
Natural macromolecules, such as proteins and nucleic acids, display various complex
functionalities in biological systems. These functionalities depend on the macromolecular …

[HTML][HTML] Hydrophilic polymers: Current trends and visions for the future

N Bayliss, BVKJ Schmidt - Progress in Polymer Science, 2023 - Elsevier
Hydrophilic polymers are a major class of polymers in polymer science. They are found in
broad range of applications from superabsorbers to drug-delivery. In recent years, a plethora …

Opportunities, challenges, and pitfalls in making, characterizing, and understanding polymer brushes

CW Pester, HA Klok, EM Benetti - Macromolecules, 2023 - ACS Publications
Polymer brushes have been theoretically described, their behavior under diverse conditions
has been modeled, and their preparation via surface-initiated polymerizations (SIPs) has …

Sha** the structure and response of surface-grafted polymer brushes via the molecular weight distribution

JC Conrad, ML Robertson - JACS Au, 2023 - ACS Publications
Breadth in the molecular weight distribution is an inherent feature of synthetic polymer
systems. While in the past this was typically considered as an unavoidable consequence of …

Topologically Precise and Discrete Bottlebrush Polymers: Synthesis, Characterization, and Structure–Property Relationships

ND Ogbonna, M Dearman, CT Cho, B Bharti, AJ Peters… - JACS Au, 2022 - ACS Publications
As the complexity of polymer structure grows, so do the challenges for develo** an
accurate understanding of their structure–property relationships. Here, the synthesis of …

Recent advances in antifouling surface polymer brushes

X Xu, Y Chang, Y Gong, Y Zhang, Y Yu… - ACS Applied Polymer …, 2023 - ACS Publications
Biofouling caused by nonspecific adsorption of biomolecules and organisms such as
proteins, cells, and bacteria to material surfaces is a significant challenge for numerous …

Local chain feature mandated self-assembly of block copolymers

Z Gan, D Zhou, Z Ma, M Xu, Z Xu, J He… - Journal of the …, 2022 - ACS Publications
This work demonstrates an effective and robust approach to regulate phase behaviors of a
block copolymer by programming local features into otherwise homogeneous linear chains …

Xanthate-supported photo-iniferter (XPI)-RAFT polymerization: facile and rapid access to complex macromolecules

AC Lehnen, J Gurke, AM Bapolisi, M Reifarth… - Chemical …, 2023 - pubs.rsc.org
Xanthate-supported photo-iniferter (XPI)-reversible addition–fragmentation chain-transfer
(RAFT) polymerization is introduced as a fast and versatile photo-polymerization strategy …

Chromatographic Separation: A Versatile Strategy to Prepare Discrete and Well-Defined Polymer Libraries

EA Murphy, C Zhang, CM Bates… - Accounts of Chemical …, 2024 - ACS Publications
Conspectus The preparation of discrete and well-defined polymers is an emerging strategy
for emulating the remarkable precision achieved by macromolecular synthesis in nature …

Controlling primary chain dispersity in network polymers: elucidating the effect of dispersity on degradation

T Shimizu, R Whitfield, GR Jones, IO Raji… - Chemical …, 2023 - pubs.rsc.org
Although dispersity has been demonstrated to be instrumental in determining many polymer
properties, current synthetic strategies predominantly focus on tailoring the dispersity of …