Ring-opening transformations of donor–acceptor cyclopropanes (DAC) with carbon-
centered nucleophiles is a simple, straight-forward approach to 1, 3-bifunctional compounds …

The interest in cyclopropane derivatives is caused by the facts that, first, the three-carbon
ring is present in quite a few natural and biologically active compounds and, second …

A general, Brønsted acid catalyzed method for the room temperature, nucleophilic ring
opening of donor–acceptor cyclopropanes in fluorinated alcohol solvent, HFIP, is described …

Alkene 1, 2-dicarbofunctionalizations are highly sought-after transformations as they enable
a rapid increase of molecular complexity in one synthetic step. Traditionally, these …

Alkyl sulfonamides are an important class of bioactive molecules. Historical syntheses have
relied on multistep sequences incorporating harsh reaction conditions. Photochemical …

Abstract Sn (OTf) 2‐catalyzed 1, 3‐aminobromination of donor–acceptor cyclopropanes with
various sulfonyl amides or electron‐poor anilines and N‐bromosuccinimide is reported …

A synthetic procedure to access 2-unsubstituted pyrrolidines and piperidines is presented. In
the presence of MgI2 as Lewis acid, donor–acceptor cyclopropanes or corresponding …

Ring-opening hydroarylation of cyclopropanes is typically limited to substrates bearing a
donor–acceptor motif. Here, the transformation is achieved for monosubstituted …

AlBr3-mediated multicomponent 1, 3-bifunctionalization of donor–acceptor cyclopropanes
using arenes and nitrosoarenes as coupling partners is presented. In the cascade, a C–C, a …

An iron (III) catalyzed tandem ring opening/1, 6-conjugate addition of cyclopropanols to p-
quinone methides leading to γ, γ-diaryl ketones has been described. This catalytic protocol …