The development of single-site catalysts has led to great potentialities for fine-tuning the
microstructure of polyolefins and polydienes. Both regioselectivity and stereoselectivity of …

Borohydride complexes of the rare earths have attracted increasing interest during the last
decade. This review aims to cover recent results over this period with respect to the …

Polymerization of β‐myrcene with neodymium borohydride‐based coordination catalysts is
very efficient, affording poly‐β‐myrcene (polymyrcene, PMy) with high selectivity. With …

The coordinative chain transfer co-and ter-polymerizations of myrcene, isoprene and styrene
have been achieved using Cp* La (BH4) 2 (THF) 2 (Cp*= pentamethylcyclopentadienyl) …

The preparation of polymers with different stereo-blocks, especially by a single catalyst, is a
promising yet highly challenging issue. In this study, we report a single rare-earth metal …

A lanthanide half‐sandwich complex and a ansa lanthanidocene have been assessed for
isoprene–styrene chain shuttling copolymerization with n‐butylethylmagnesium (BEM). In …

Chain shuttling polymerization (CSP) has exhibited unique privilege to combine monomer
sequences of different properties into one macromolecular chain, which, however, is difficult …

Tap** facile and efficient strategies for in-situ end-functionalization of polydiene
elastomers has been pursued for scientists for decades. This has been especially prominent …

Multiblock copolymers of cis-1, 4-and trans-1, 4-polybutadiene (PBD) have shown exciting
and unique elastic properties. But the catalyst that can steadily regulate the content and the …

The present investigation involves the coordinative chain transfer polymerization (CCTP) of
biobased terpenes in order to obtain sustainable polymers from myrcene (My) and …