Toward heterometallic single-molecule magnets: Synthetic strategy, structures and properties of 3d–4f discrete complexes

K Liu, W Shi, P Cheng - Coordination Chemistry Reviews, 2015 - Elsevier
Abstract 3d–4f heterometallic discrete complexes have enjoyed increasing attraction in
recent decades because of their potential advantages to create new single-molecule …

[HTML][HTML] The coordination chemistry and magnetism of some 3d–4f and 4f amino-polyalcohol compounds

JW Sharples, D Collison - Coordination chemistry reviews, 2014 - Elsevier
Abstract Triethanolamine, teaH 3, and diethanolamine, RdeaH 2, 3d–4f and 4f compounds
demonstrate an enormous variety in their structure and bonding. This review examines the …

What do 3d-4f butterflies tell us?

Y Peng, AK Powell - Coordination Chemistry Reviews, 2021 - Elsevier
The most studied examples of 3d-4f based single molecule magnets (SMMs) and their
coordination cluster counterparts is that of the 3d-4f butterfly systems which provide a test …

Systematic Study of a Family of Butterfly-Like {M2Ln2} Molecular Magnets (M = MgII, MnIII, CoII, NiII, and CuII; Ln = YIII, GdIII, TbIII, DyIII, HoIII, and ErIII)

E Moreno Pineda, NF Chilton, F Tuna… - Inorganic …, 2015 - ACS Publications
A family of 3d–4f [MII2LnIII2 (μ3-OH) 2 (O2C t Bu) 10] 2–“butterflies”(where MII= Mg, Co, Ni,
and Cu; LnIII= Y, Gd, Tb, Dy, Ho, and Er) and [MnIII2LnIII2 (μ3-O) 2 (O2C t Bu) 10] 2 …

Structural and magnetic properties of some lanthanide (Ln= Eu (III), Gd (III) and Nd (III)) cyanoacetate polymers: field-induced slow magnetic relaxation in the Gd and …

A Arauzo, A Lazarescu, S Shova, E Bartolomé… - Dalton …, 2014 - pubs.rsc.org
The lanthanide (III) cyanoacetate complexes of the formula {[Ln2 (CNCH2COO) 6 (H2O) 4]·
2H2O} n, where Ln= Eu (1), Gd (2), Nd (3), have been prepared and characterized by X-ray …

Magnetic anisotropy and mechanism of magnetic relaxation in Er (III) single-ion magnets

SK Singh, T Gupta, G Rajaraman - Inorganic chemistry, 2014 - ACS Publications
Magnetic anisotropy is a key component in the design of single-molecule magnets (SMMs)
possessing a large barrier height for magnetization reversal. Lanthanide-based SMMs are …

Mechanism of magnetisation relaxation in {M III2 Dy III2}(M= Cr, Mn, Fe, Al)“Butterfly” complexes: how important are the transition metal ions here?

Y Peng, MK Singh, V Mereacre, CE Anson… - Chemical …, 2019 - pubs.rsc.org
We describe the synthesis, characterisation and magnetic studies of four tetranuclear,
isostructural “butterfly” heterometallic complexes:[MIII2LnIII2 (μ3-OH) 2 (p-Me-PhCO2) 6 (L) …

Ringing the changes in Fe III/Yb III cyclic coordination clusters

A Baniodeh, CE Anson, AK Powell - Chemical Science, 2013 - pubs.rsc.org
Five [FeIIImYbIIIn] Cyclic Coordination Clusters (CCCs) which show completely different
arrangements of their cyclic cores have been synthesised and characterised. These …

The role of coordinated solvent on Co (ii) ions in tuning the single molecule magnet properties in a {Co II2 Dy III2} system

Y Peng, V Mereacre, CE Anson, AK Powell - Dalton Transactions, 2017 - pubs.rsc.org
Three defect-dicubane coordination clusters related to our previously reported butterfly
compound,[Co2Dy2 (L) 4 (NO3) 2 (THF) 2]· 4THF (1) and formulated as [Co2Dy2 (L) 4 (NO3) …

Experimental and theoretical investigations of four 3d–4f butterfly single-molecule magnets

HH Zou, LB Sheng, FP Liang, ZL Chen… - Dalton Transactions, 2015 - pubs.rsc.org
The syntheses, structures, and characterization of four 3d–4f butterfly clusters are described.
With different polyhydroxy Schiff-base ligands 2-(((2-hydroxy-3-methoxyphenyl) methylene) …