Two-dimensional metal-organic framework materials: synthesis, structures, properties and applications
Among the recent developments in metal-organic frameworks (MOFs), porous layered
coordination polymers (CPs) have garnered attention due to their modular nature and …
coordination polymers (CPs) have garnered attention due to their modular nature and …
Spin crossover with thermal hysteresis: practicalities and lessons learnt
S Brooker - Chemical Society Reviews, 2015 - pubs.rsc.org
The observation of spin crossover with thermal hysteresis loops of more than a few Kelvin
remains relatively uncommon and unpredictable, so is a relatively underdeveloped, but …
remains relatively uncommon and unpredictable, so is a relatively underdeveloped, but …
Thermo-, piezo-, photo-and chemo-switchable spin crossover iron (II)-metallocyanate based coordination polymers
MC Munoz, JA Real - Coordination Chemistry Reviews, 2011 - Elsevier
The design of coordination polymers (CPs) with switch and memory functions is an important
subject of current interest in the search for new advanced materials with potential …
subject of current interest in the search for new advanced materials with potential …
Dicyanometallates as model extended frameworks
We report the structures of eight new dicyanometallate frameworks containing molecular
extra-framework cations. These systems include a number of hybrid inorganic–organic …
extra-framework cations. These systems include a number of hybrid inorganic–organic …
Remarkable scan rate dependence for a highly constrained dinuclear iron (II) spin crossover complex with a wide thermal hysteresis loop
The abrupt [HS-HS]↔ localized [HS-LS] spin crossovers of a new triazole-based diiron (II)
complex result in a record-equaling thermal hysteresis loop width for a dinuclear complex (Δ …
complex result in a record-equaling thermal hysteresis loop width for a dinuclear complex (Δ …
Two-Step Spin Crossover in Hofmann-Type Coordination Polymers [Fe(2-phenylpyrazine)2{M(CN)2}2] (M = Ag, Au)
Two 2D Hofmann-type complexes of the composition [Fe (Phpz) 2 {M (CN) 2} 2](where
Phpz= 2-phenylpyrazine; M= Ag, Au) have been synthesized, and their spin-crossover …
Phpz= 2-phenylpyrazine; M= Ag, Au) have been synthesized, and their spin-crossover …
Hofmann‐Type Cyanide Bridged Coordination Polymers for Advanced Functional Nanomaterials
Since the discovery of Hofmann clathrates of inorganic cyanide bridged coordination
polymers (Hofmann‐type CN‐CPs), extensive research is done to understand their behavior …
polymers (Hofmann‐type CN‐CPs), extensive research is done to understand their behavior …
Spin crossover in FeII cyanometallic frameworks
Spin-crossover (SCO) compounds represent a huge class of switchable coordination
complexes that can change their electronic configurations under the influence of different …
complexes that can change their electronic configurations under the influence of different …
Multiple Bistability and Tristability with Dual Spin-State Conversions in [Fe(dpp)2][Ni(mnt)2]2·MeNO2
M Nihei, H Tahira, N Takahashi, Y Otake… - Journal of the …, 2010 - ACS Publications
The multicomponent system of [Fe (dpp) 2][Ni (mnt) 2] 2· MeNO2 (1; dpp= 2, 6-bis (pyrazol-1-
yl) pyridine and mnt= maleonitriledithiolate) was prepared by the reaction of [Fe (dpp) …
yl) pyridine and mnt= maleonitriledithiolate) was prepared by the reaction of [Fe (dpp) …
Synthesis and Characterisation of a New Series of Bistable Iron (II) Spin‐Crossover 2D Metal–Organic Frameworks
V Martínez, AB Gaspar, MC Muñoz… - … A European Journal, 2009 - Wiley Online Library
Twelve coordination polymers with formula {Fe (3‐Xpy) 2 [MII (CN) 4]}(MII: Ni, Pd, Pt; X: F, Cl,
Br, I; py: pyridine) have been synthesised, and their crystal structures have been determined …
Br, I; py: pyridine) have been synthesised, and their crystal structures have been determined …