Nucleobase synthesis in interstellar ices

Y Oba, Y Takano, H Naraoka, N Watanabe… - Nature …, 2019 - nature.com
The synthesis of nucleobases in natural environments, especially in interstellar molecular
clouds, is the focus of a long-standing debate regarding prebiotic chemical evolution. Here …

From sunscreens to medicines: Can a dissipation hypothesis explain the beneficial aspects of many plant compounds?

AVW Nunn, GW Guy, SW Botchway… - Phytotherapy …, 2020 - Wiley Online Library
Medicine has utilised plant‐based treatments for millennia, but precisely how they work is
unclear. One approach is to use a thermodynamic viewpoint that life arose by dissipating …

Transmission electron microscopy study of the morphology of ices composed of H2O, CO2, and CO on refractory grains

A Kouchi, M Tsuge, T Hama, Y Oba… - The Astrophysical …, 2021 - iopscience.iop.org
It has been implicitly assumed that ices on grains in molecular clouds and protoplanetary
disks are formed by homogeneous layers regardless of their composition or crystallinity. To …

Uncovering the chiral bias of meteoritic isovaline through asymmetric photochemistry

J Bocková, NC Jones, J Topin, SV Hoffmann… - Nature …, 2023 - nature.com
Systematic enrichments of l-amino acids in meteorites is a strong indication that biological
homochirality originated beyond Earth. Although still unresolved, stellar UV circularly …

Diffusion activation energy and desorption activation energy for astrochemically relevant species on water ice show no clear relation

K Furuya, T Hama, Y Oba, A Kouchi… - The Astrophysical …, 2022 - iopscience.iop.org
The activation energies for desorption (E des) and for surface diffusion (E sd) of adsorbed
molecules on dust grains are two of the most important parameters for the chemistry in the …

Infrared multiple‐angle incidence resolution spectrometry for vapor‐deposited amorphous water

T Nagasawa, N Numadate… - Journal of Raman …, 2022 - Wiley Online Library
Infrared multiple‐angle incidence resolution spectrometry (IR‐MAIRS) is a recently
developed spectroscopic technique that combines oblique incidence transmission …

Direct measurements of activation energies for surface diffusion of CO and CO2 on amorphous solid water using in situ transmission electron microscopy

A Kouchi, K Furuya, T Hama, T Chigai… - The Astrophysical …, 2020 - iopscience.iop.org
The importance of the activation energy of surface diffusion (E sd) of adsorbed molecules on
amorphous solid water (ASW) has been widely discussed in terms of chemical reactions on …

Theoretical analysis of crystallization by homogeneous nucleation of water droplets

KK Tanaka, Y Kimura - Physical chemistry chemical physics, 2019 - pubs.rsc.org
We propose a novel method for analyzing the crystallization process from supercooled water
droplets. The method, which is based on nucleation theory, simultaneously evolves …

The EXCITING experiment exploring the behavior of nitrogen and noble gases in interstellar ice analogs

MG Almayrac, DV Bekaert, MW Broadley… - The Planetary …, 2022 - iopscience.iop.org
Comets represent some of the most pristine bodies in our solar system and can provide a
unique insight into the chemical makeup of the early solar system. Due to their icy volatile …

Formation of chiral CO polyhedral crystals on icy interstellar grains

A Kouchi, M Tsuge, T Hama, H Niinomi… - Monthly notices of …, 2021 - academic.oup.com
The crystallinity and morphology of solid carbon monoxide (CO) on icy interstellar grains
were examined by observing the deposition, crystallization, and UV and electrons irradiation …