Cobalt corroles: Synthesis and applications
Cobalt corrole chemistry has become its own corpus of corrole literature in recent years, with
findings involving synthesis, catalysis, sensing, electrocatalysis, etc reported with increasing …
findings involving synthesis, catalysis, sensing, electrocatalysis, etc reported with increasing …
Synthesis, Spectral, Redox, and Sensing Studies of β-Dicyanovinyl-Appended Corroles and Their Metal Complexes
A new family of β-dicyanovinyl (DCV)-appended corroles represented as MTPC (MN)(where
M= 3H, Cu, Ag, and Co (PPh3) and MN= malononitrile and TPC= 5, 10, 15-triphenylcorrole) …
M= 3H, Cu, Ag, and Co (PPh3) and MN= malononitrile and TPC= 5, 10, 15-triphenylcorrole) …
Hypercorroles Formed via the Tail that Wagged the Dog: Charge Transfer Interactions from Innocent Corroles to Meso-Nitrophenyl Substituents
WR Osterloh, N Desbois, CP Gros… - Inorganic Chemistry, 2022 - ACS Publications
A series of cobalt nitrophenylcorroles were spectrally characterized in CH2Cl2, and under
certain solution conditions, several compounds were shown to exhibit hypercorrole spectra …
certain solution conditions, several compounds were shown to exhibit hypercorrole spectra …
Cobalt, Iron, and Manganese Metallocorroles in Catalytic Oxidation of Water. An Overview of the Synthesis, Selected Redox and Electronic Properties, and Catalytic …
VA Vaillard, PD Nieres, SE Vaillard… - European Journal of …, 2022 - Wiley Online Library
Metallocorroles have emerged as interesting and versatile catalysts for a variety of redox
reactions. These include clean‐energy related small‐molecule activation reactions such as …
reactions. These include clean‐energy related small‐molecule activation reactions such as …
Altering the Site of Electron Abstraction in Cobalt Corroles via meso-Trifluoromethyl Substituents
A mono-DMSO cobalt meso-CF3 corrole, formulated as (CF3) 3CorCo (DMSO), where (CF3)
3Cor is the trianion of 5, 10, 15-tris (trifluoromethyl) corrole, was synthesized and …
3Cor is the trianion of 5, 10, 15-tris (trifluoromethyl) corrole, was synthesized and …
Cobalt corroles as electrocatalysts for water oxidation: Strong effect of substituents on catalytic activity
Two Co (III) complexes (1Py 2 and 2Py 2) of new corrole ligands H 3 L1 (5, 15-bis (p-
methylcarboxyphenyl)-10-(o-methylcarboxyphenyl) corrole) and H 3 L2 (5, 15-bis (p …
methylcarboxyphenyl)-10-(o-methylcarboxyphenyl) corrole) and H 3 L2 (5, 15-bis (p …
A DMRG/CASPT2 investigation of metallocorroles: quantifying ligand noninnocence in archetypal 3d and 4d element derivatives
Hybrid density functional theory (B3LYP) and density matrix renormalization group (DMRG)
theory have been used to quantitatively compare the degree of ligand noninnocence …
theory have been used to quantitatively compare the degree of ligand noninnocence …
Old dog, new tricks: Innocent, five-coordinate cyanocobalt corroles
WR Osterloh, N Desbois, V Quesneau… - Inorganic …, 2020 - ACS Publications
Three mono-CN ligated anionic cobalt A3-triarylcorroles were synthesized and investigated
as to their spectroscopic and electrochemical properties in CH2Cl2, pyridine (Py), and …
as to their spectroscopic and electrochemical properties in CH2Cl2, pyridine (Py), and …
The Difficult Marriage of Triarylcorroles with Zinc and Nickel Ions
The coordination chemistry of corrole has witnessed a great improvement in the past few
years and its Periodic Table has been widened to be so large that it is compared with that of …
years and its Periodic Table has been widened to be so large that it is compared with that of …
Minding our P-block and Q-bands: paving inroads into main group corrole research to help instil broader potential
Main group chemistry is often considered less “dynamic” than transition metal (TM)
chemistry because of predictable VSEPR-based central atom geometries, relatively slower …
chemistry because of predictable VSEPR-based central atom geometries, relatively slower …