Metal–organic frameworks based on infinite secondary building units: recent progress and future outlooks

J Guo, X Xue, H Yu, Y Duan, F Li, Y Lian… - Journal of Materials …, 2022 - pubs.rsc.org
Metal–organic frameworks (MOFs) are a type of inorganic–organic hybrid connected by
organic ligands and discrete metal ions/metallic secondary building units (SBUs). Recently …

Role of metal selection in the radiation stability of isostructural M-UiO-66 metal–organic frameworks

AM Hastings, M Fairley, MC Wasson… - Chemistry of …, 2022 - ACS Publications
Robust and versatile metal–organic frameworks (MOFs) have emerged as sophisticated
scaffolds to meet the critical needs of the nuclear community, but their performance depends …

Beyond the conventional limitation of photocycloaddition reaction in the roomy nanospace of a metal–organic framework

M Nakagawa, S Kusaka, A Kiyose… - Journal of the …, 2023 - ACS Publications
Topochemical reactions provide selective products based on the molecular position;
however, they generally require molecules to be placed in strictly limited orientations and …

Building robust metal-organic frameworks with premade ligands

YL Hou, C Yang, Z Yang, H Zhou, L Guo, J Guo… - Coordination Chemistry …, 2024 - Elsevier
To date, metal–organic frameworks (MOFs) with diverse topological structures and
functionalities have proven to be versatile materials with applications in catalysis, drug …

f‐block MOFs: A Pathway to Heterometallic Transuranics

KC Park, P Kittikhunnatham, J Lim… - Angewandte Chemie …, 2023 - Wiley Online Library
A novel series of heterometallic f‐block‐frameworks including the first examples of
transuranic heterometallic 238U/239Pu‐metal–organic frameworks (MOFs) and a novel …

Capture instead of release: defect-modulated radionuclide leaching kinetics in metal–organic frameworks

KC Park, CR Martin, GA Leith… - Journal of the …, 2022 - ACS Publications
Comparison of defect-controlled leaching-kinetics modulation of metal–organic frameworks
(MOFs) and porous functionalized silica-based materials was performed on the example of a …

Stability of metal-organic frameworks towards β-ray irradiation: Role of organic groups

X Ding, S **ao, T Wang, Z Zeng, X Zhao… - … and Mesoporous Materials, 2023 - Elsevier
Available online Metal-organic frameworks (MOFs) have emerged high potentials in
recovering nuclides, while their performances preferentially depend on the stability under …

Selective Crystallization of a Highly Radiation-Resistant Isonicotinic Acid-Based Metal–Organic Framework as a Primary Actinide Waste Form

K Lv, M Patzschke, J März, E Bazarkina… - ACS Materials …, 2023 - ACS Publications
Isonicotinic acid (INA), as a prototypical N, O-donor bifunctional ligand, has demonstrated its
ability to differentiate Th4+ from representative ions for products in spent nuclear fuels (Cs+ …

[HTML][HTML] Radiation resistant metal–organic frameworks for the production of high specific activity 51Cr by the Szilard-Chalmers effect

C Ma, I Sánchez-García, R Wang, H Galán… - Separation and …, 2025 - Elsevier
Abstract Chromium-51 (51 Cr) is an attractive radionuclide for diagnosis, which is usually
applied for red cells and platelet radiolabeling. However, commercially available 51 Cr …

Radiation-induced solid-state transformations of uranyl peroxides

M Fairley, DE Felton, GE Sigmon… - Inorganic …, 2021 - ACS Publications
Single-crystal X-ray diffraction studies of pristine and γ-irradiated Ca2 [UO2 (O2) 3]· 9H2O
reveal site-specific atomic-scale changes during the solid-state progression from a …