Metal–organic frameworks based on infinite secondary building units: recent progress and future outlooks
Metal–organic frameworks (MOFs) are a type of inorganic–organic hybrid connected by
organic ligands and discrete metal ions/metallic secondary building units (SBUs). Recently …
organic ligands and discrete metal ions/metallic secondary building units (SBUs). Recently …
Role of metal selection in the radiation stability of isostructural M-UiO-66 metal–organic frameworks
Robust and versatile metal–organic frameworks (MOFs) have emerged as sophisticated
scaffolds to meet the critical needs of the nuclear community, but their performance depends …
scaffolds to meet the critical needs of the nuclear community, but their performance depends …
Beyond the conventional limitation of photocycloaddition reaction in the roomy nanospace of a metal–organic framework
M Nakagawa, S Kusaka, A Kiyose… - Journal of the …, 2023 - ACS Publications
Topochemical reactions provide selective products based on the molecular position;
however, they generally require molecules to be placed in strictly limited orientations and …
however, they generally require molecules to be placed in strictly limited orientations and …
Building robust metal-organic frameworks with premade ligands
To date, metal–organic frameworks (MOFs) with diverse topological structures and
functionalities have proven to be versatile materials with applications in catalysis, drug …
functionalities have proven to be versatile materials with applications in catalysis, drug …
f‐block MOFs: A Pathway to Heterometallic Transuranics
A novel series of heterometallic f‐block‐frameworks including the first examples of
transuranic heterometallic 238U/239Pu‐metal–organic frameworks (MOFs) and a novel …
transuranic heterometallic 238U/239Pu‐metal–organic frameworks (MOFs) and a novel …
Capture instead of release: defect-modulated radionuclide leaching kinetics in metal–organic frameworks
Comparison of defect-controlled leaching-kinetics modulation of metal–organic frameworks
(MOFs) and porous functionalized silica-based materials was performed on the example of a …
(MOFs) and porous functionalized silica-based materials was performed on the example of a …
Stability of metal-organic frameworks towards β-ray irradiation: Role of organic groups
X Ding, S **ao, T Wang, Z Zeng, X Zhao… - … and Mesoporous Materials, 2023 - Elsevier
Available online Metal-organic frameworks (MOFs) have emerged high potentials in
recovering nuclides, while their performances preferentially depend on the stability under …
recovering nuclides, while their performances preferentially depend on the stability under …
Selective Crystallization of a Highly Radiation-Resistant Isonicotinic Acid-Based Metal–Organic Framework as a Primary Actinide Waste Form
K Lv, M Patzschke, J März, E Bazarkina… - ACS Materials …, 2023 - ACS Publications
Isonicotinic acid (INA), as a prototypical N, O-donor bifunctional ligand, has demonstrated its
ability to differentiate Th4+ from representative ions for products in spent nuclear fuels (Cs+ …
ability to differentiate Th4+ from representative ions for products in spent nuclear fuels (Cs+ …
[HTML][HTML] Radiation resistant metal–organic frameworks for the production of high specific activity 51Cr by the Szilard-Chalmers effect
Abstract Chromium-51 (51 Cr) is an attractive radionuclide for diagnosis, which is usually
applied for red cells and platelet radiolabeling. However, commercially available 51 Cr …
applied for red cells and platelet radiolabeling. However, commercially available 51 Cr …
Radiation-induced solid-state transformations of uranyl peroxides
Single-crystal X-ray diffraction studies of pristine and γ-irradiated Ca2 [UO2 (O2) 3]· 9H2O
reveal site-specific atomic-scale changes during the solid-state progression from a …
reveal site-specific atomic-scale changes during the solid-state progression from a …