Glassy dynamics of soft matter under 1D confinement: How irreversible adsorption affects molecular packing, mobility gradients and orientational polarization in thin …

S Napolitano, S Capponi, B Vanroy - The European Physical Journal E, 2013 - Springer
The structural dynamics of polymers and simple liquids confined at the nanometer scale has
been intensively investigated in the last two decades in order to test the validity of theories …

Irreversible adsorption of polymer melts and nanoconfinement effects

S Napolitano - Soft Matter, 2020 - pubs.rsc.org
For almost a decade, growing experimental evidence has revealed a strong correlation
between the properties of nanoconfined polymers and the number of chains irreversibly …

Formation mechanism of high-density, flattened polymer nanolayers adsorbed on planar solids

N Jiang, J Shang, X Di, MK Endoh, T Koga - Macromolecules, 2014 - ACS Publications
Thermal annealing is one of the most indispensable polymer fabrication processes and
plays essential roles in controlling morphologies and properties of polymeric materials. We …

Affinity of Polystyrene Films to Hydrogen-Passivated Silicon and Its Relevance to the Tg of the Films

Y Fujii, Z Yang, J Leach, H Atarashi, K Tanaka… - …, 2009 - ACS Publications
Qualitatively different thickness dependences have been observed in the glass transition
temperature, T g, of polystyrene (PS) films supported by hydrogen-passivated silicon (H− Si) …

Interfacial dynamics and rheology of polymer-grafted nanoparticles at air–water and xylene–water interfaces

NJ Alvarez, SL Anna, T Saigal, RD Tilton, LM Walker - Langmuir, 2012 - ACS Publications
Particle-stabilized emulsions and foams offer a number of advantages over traditional
surfactant-stabilized systems, most notably a greater stability against coalescence and …

Non-equilibrium in adsorbed polymer layers

B O'Shaughnessy, D Vavylonis - Journal of physics: condensed …, 2004 - iopscience.iop.org
High molecular weight polymer solutions have a powerful tendency to deposit adsorbed
layers when exposed to even mildly attractive surfaces. The equilibrium properties of these …

Single-molecule observation of long jumps in polymer adsorption

C Yu, J Guan, K Chen, SC Bae, S Granick - ACS nano, 2013 - ACS Publications
Single-molecule fluorescence imaging of adsorption onto initially bare surfaces shows that
polymer chains need not localize immediately after arrival. In a system optimized to present …

Single-molecule tracking of polymer surface diffusion

MJ Skaug, JN Mabry, DK Schwartz - Journal of the American …, 2014 - ACS Publications
The dynamics of polymers adsorbed to a solid surface are important in thin-film formation,
adhesion phenomena, and biosensing applications, but they are still poorly understood …

Exchange lifetimes of the bound polymer layer on silica nanoparticles

AM Jimenez, D Zhao, K Misquitta, J Jestin… - ACS Macro …, 2019 - ACS Publications
Understanding the structure and dynamics of the bound polymer layer (BL) that forms on
favorably interacting nanoparticles (NPs) is critical to revealing the mechanisms responsible …

Thermal characterization of PMMA thin films using modulated differential scanning calorimetry

CE Porter, FD Blum - Macromolecules, 2000 - ACS Publications
Modulated differential scanning calorimetry was used to probe the thermal behavior of poly
(methyl methacrylate)(PMMA) adsorbed onto silica from solution and subsequently dried …