In the vast majority of top-selling pharmaceutical and industrial products, phenolic structural
motifs are highly prevalent. Non-functionalized simple phenols serve as building blocks in …

Over the decades, functionalized heteroaromatic compounds and their scaffolds have drawn
significant attention in synthetic organic chemistry as well as in interdisciplinary sciences …

Owing to its unique physical properties, fluorine is often used to open up new reaction
channels. In this report, we establish a cooperation of [5, 5]‐rearrangement and fluorine …

Zweifel reaction is a powerful strategy to construct olefins from alkenyl tetracoordinate
borons in organoboron chemistry, however, it usually only involves one functional group …

Regioselectively arylated heteroarenes are privileged scaffolds with remarkable biological
and optoelectronic properties. Traditional arylation approaches based on the transition …

Treatment of multisubstituted NH-enesulfinamides with tosyl isocyanate (TsNCO) at room
temperature results in the formation of α-tosylcarbamoyloxy N-sulfenyl ketimines with high …

Treatment of 2-methylsulfinylbenzazoles with triflic anhydride in the presence of phenols
yields the corresponding 4-(p-hydroxyphenyl)-2-methylsulfanylbenzazoles. This …

Starting with vinyl sulfoxides and propargyl silane, the Au (I)-catalyzed asymmetric [3, 3]-
sigmatropic rearrangement of sulfonium intermediates furnished, after a protodemetallation …

A general one-pot, two-step synthesis of benzothiophenes is presented. First, the Morita–
Baylis–Hillman (MBH) type sulfonium-[3, 3]-rearrangement of aryl sulfoxides with …

An unusual benzofuran synthesis from 2, 6-disubstituted phenols and alkynyl sulfoxides is
disclosed. Various highly substituted benzofurans were synthesized via the charge …