Alkene-derived radical cations are versatile reactive intermediates and have been widely
applied in the construction of complex functionalized molecules and cyclic systems for …

Synthetic chemists have long focused on selective C (sp 3)–N bond-forming approaches in
response to the high value of this motif in natural products, pharmaceutical agents and …

Electron‐deficient acridones and in situ generated acridinium salts are reported as potent,
closed‐shell photooxidants that undergo surprising mechanisms. When bridging acyclic …

We report here an efficient and highly diastereoselective intermolecular anti-Markovnikov
hydroamination of unactivated alkenes with aliphatic azides in the presence of silane. The …

Abstract β‐(Hetero) arylethylamines appear in a myriad of pharmaceuticals due to their
broad spectrum of biological properties, making them prime candidates for drug discovery …

Primary aliphatic amines are crucial, and at the very least, millions of tons are required every
year. Therefore, significant interest has grown in finding new chemical routes for their …

(Hetero) arylethylamines are privileged substructures in pharmaceuticals, agrochemicals,
and other bioactive compounds. In principle, the amino–(hetero) arylation of olefins …

Acyl radicals have been generated from the decarboxylation of α-oxocarboxylic acids by
using a readily accessible organic pyrimidopteridine photoredox catalyst under ultraviolet-A …

Porous materials‐based heterogeneous photocatalysts, performing selective organic
transformations, are increasing the applicability of photocatalytic reactions due to their ability …

Here, we report the synthesis and structures of two thermally stable base-free
heterobimetallic benzhydryl complexes {[(pt BuC6H4) 2CH] 3M} K (M= Yb (II) and Ca (II)) …