Redox-and Charge-State Dependent Trends in 5, 6, and 7-Membered Boron Heterocycles: A Neutral Ligand Coordination Chemistry Approach to Boracyclic Cations …
KK Hollister, KE Wentz… - Accounts of Chemical …, 2024 - ACS Publications
Conspectus Boron heterocycles represent an important subset of heteroatom-incorporated
rings, attracting attention from organic, inorganic, and materials chemists. The empty pz …
rings, attracting attention from organic, inorganic, and materials chemists. The empty pz …
Unveiling Three Interconvertible Redox States of Boraphenalene
CL Deng, KK Hollister, A Molino, BYE Tra… - Journal of the …, 2024 - ACS Publications
Neutral 1-boraphenalene displays the isoelectronic structure of the phenalenyl carbocation
and is expected to behave as an attractive organoboron multi-redox system. However, the …
and is expected to behave as an attractive organoboron multi-redox system. However, the …
Unlocking Biradical Character in Diborepins
KK Hollister, A Molino, N Jones, VVV Le… - Journal of the …, 2024 - ACS Publications
Systems that possess open-and closed-shell behavior attract significant attention from
researchers due to their inherent redox and charge transport properties. Herein, we report …
researchers due to their inherent redox and charge transport properties. Herein, we report …
Approaching Dianionic Tetraoxadiborecine Macrocycles: 10‐Membered Bora‐Crown Ethers Incorporating Borafluorenate Units
The addition of non‐benzenoid quinones, acenapthenequinone or aceanthrenequinone, to
the 9‐carbene‐9‐borafluorene monoanion (1) affords the first examples of dianionic 10 …
the 9‐carbene‐9‐borafluorene monoanion (1) affords the first examples of dianionic 10 …
Borafluorene-Mediated Sulfur Activation: Isolation of Boryl-Linked S7 and S8 Catenates and Related Chalcogenide Molecules
NC Frey, KK Hollister, P Müller, DA Dickie… - Inorganic …, 2024 - ACS Publications
Although the activation of elemental sulfur by main group compounds is well-documented in
the literature, the products of such reactions are often heterocyclic in nature. However, the …
the literature, the products of such reactions are often heterocyclic in nature. However, the …
Photochemically and Thermally Generated BN-Doped Borafluorenate Heterocycles via Intramolecular Staudinger-Type Reactions
A series of BN-incorporated borafluorenate heterocycles, bis (borafluorene-phosphinimine)
s (11–15), have been formed via intra molecular Staudinger-type reactions. The reactions …
s (11–15), have been formed via intra molecular Staudinger-type reactions. The reactions …
Mono-and Bis-Phosphine Promoted Incorporation of Boron, Nitrogen, and Phosphorus into Heterocycles via Staudinger Reactions of Borafluorene Azides
We report the synthesis and characterization of a series of BNP-incorporated borafluorenate
heterocycles formed via thermolysis reactions of pyridylphosphine and bis (phosphine) …
heterocycles formed via thermolysis reactions of pyridylphosphine and bis (phosphine) …
Enhancement of Circularly Polarized Luminescence Brightness of Schiff‐Base Diphenylboron and 9‐Borafluoren‐9‐yl Complexes
M Ikeshita, S Watanabe, T Oka, A Kuroda… - …, 2024 - Wiley Online Library
A series of diphenylboron and 9‐borafluoren‐9‐yl complexes with chiral Schiff‐base ligands
was synthesized and characterized by NMR spectroscopy. X‐ray diffraction analysis …
was synthesized and characterized by NMR spectroscopy. X‐ray diffraction analysis …
Theoretical Investigations on the Electronic Structure and Molecular Properties of Carbene-Stabilised Boron Heterocycles and Beryllium Complexes
A Molino - 2024 - opal.latrobe.edu.au
The introduction of stable N-heterocyclic carbenes (NHCs) and carbone ligands has
revolutionised main-group organometallic chemistry, enabling unprecedented exploration of …
revolutionised main-group organometallic chemistry, enabling unprecedented exploration of …