Complementary probes for the electrochemical interface

E Pastor, Z Lian, L **a, D Ecija… - Nature Reviews …, 2024 - nature.com
The functions of electrochemical energy conversion and storage devices rely on the
dynamic junction between a solid and a fluid: the electrochemical interface (EI). Many …

The kinetics of metal oxide photoanodes from charge generation to catalysis

S Corby, RR Rao, L Steier, JR Durrant - Nature Reviews Materials, 2021 - nature.com
Generating charge carriers with lifetimes long enough to drive catalysis is a critical aspect for
photoelectrochemical and photocatalytic systems, and a key determinant of their efficiency …

Realizing Two-Electron Transfer in Ni(OH)2 Nanosheets for Energy Storage

J Kang, Y Xue, J Yang, Q Hu, Q Zhang… - Journal of the …, 2022 - ACS Publications
The theoretical capacity of a given electrode material is ultimately determined by the number
of electrons transferred in each redox center. The design of multi-electron transfer processes …

In Situ UV–Vis–NIR Absorption Spectroscopy and Catalysis

ML Bols, J Ma, F Rammal, D Plessers, X Wu… - Chemical …, 2024 - ACS Publications
This review highlights in situ UV–vis–NIR range absorption spectroscopy in catalysis. A
variety of experimental techniques identifying reaction mechanisms, kinetics, and structural …

Spectroelectrochemical analysis of the water oxidation mechanism on doped nickel oxides

RR Rao, S Corby, A Bucci… - Journal of the …, 2022 - ACS Publications
Metal oxides and oxyhydroxides exhibit state-of-the-art activity for the oxygen evolution
reaction (OER); however, their reaction mechanism, particularly the relationship between …

Benchmarking of oxygen evolution catalysts on porous nickel supports

A Peugeot, CE Creissen, D Karapinar, HN Tran… - Joule, 2021 - cell.com
Active and inexpensive oxygen evolution reaction (OER) electrocatalysts are needed for
energy-efficient electrolysis applications. Objective comparison between OER catalysts has …

Tracking high-valent surface iron species in the oxygen evolution reaction on cobalt iron (oxy) hydroxides

S Lee, A Moysiadou, YC Chu, HM Chen… - Energy & Environmental …, 2022 - pubs.rsc.org
The oxygen evolution reaction (OER) is the bottleneck reaction of water splitting, which can
be used to generate green hydrogen from renewable electricity. Cobalt iron oxyhydroxides …

Investigation of nickel iron layered double hydroxide for water oxidation in different pH electrolytes

Q **e, D Ren, L Bai, R Ge, W Zhou, L Bai, W **e… - Chinese Journal of …, 2023 - Elsevier
Nickel iron layered double hydroxide (NiFe LDH) is one of the best oxygen evolution
reaction (OER) catalysts in alkaline electrolytes. However, it performs poorly in neutral …

Latest advances in in situ and operando X-ray-based techniques for the characterisation of photoelectrocatalytic systems

M Barawi, CA Mesa, L Collado… - Journal of Materials …, 2024 - pubs.rsc.org
In situ and operando X-ray techniques have emerged as powerful tools for unravelling the
complex mechanisms underlying photoelectrochemical transformations. These techniques …

Unraveling the role of particle size and nanostructuring on the oxygen evolution activity of Fe-doped NiO

RR Rao, A Bucci, S Corby, B Moss, C Liang… - ACS …, 2024 - ACS Publications
Nickel-based oxides and oxyhydroxide catalysts exhibit state-of-the-art activity for the
sluggish oxygen evolution reaction (OER) under alkaline conditions. A widely employed …