Molecular main group metal hydrides
This review serves to document advances in the synthesis, versatile bonding, and reactivity
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …
Recent progress on NHC-stabilized early transition metal (group 3–7) complexes: Synthesis and applications
C Romain, S Bellemin-Laponnaz, S Dagorne - Coordination Chemistry …, 2020 - Elsevier
The present paper comprehensively reviews group 3–7 metal NHC complexes reported
since 2014, with emphasis on their current applications and fundamental reactivity. Thanks …
since 2014, with emphasis on their current applications and fundamental reactivity. Thanks …
Low-Coordinate NHC–Zinc Hydride Complexes Catalyze Alkyne C–H Borylation and Hydroboration Using Pinacolborane
RJ Procter, M Uzelac, J Cid, PJ Rushworth… - ACS …, 2019 - ACS Publications
Organozinc compounds containing sp, sp2, and sp3 C–Zn moieties undergo transmetalation
with pinacolborane (HBPin) to produce Zn–H species and organoboronate esters (RBPin) …
with pinacolborane (HBPin) to produce Zn–H species and organoboronate esters (RBPin) …
Zinc Catalyzed Hydroboration of Esters and Nitriles with Pinacolborane
We developed a bench-stable iminopyridine-ligated zinc complex for the effective catalytic
hydroboration of esters and nitriles under solvent-free conditions. Various esters and nitriles …
hydroboration of esters and nitriles under solvent-free conditions. Various esters and nitriles …
Zinc Hydride Catalyzed Chemoselective Hydroboration of Isocyanates: Amide Bond Formation and C= O Bond Cleavage
Herein, a remarkable conjugated bis‐guanidinate (CBG) supported zinc hydride,[{LZnH} 2;
L={(ArHN)(ArN)− C= N− C=(NAr)(NHAr); Ar= 2, 6‐Et2‐C6H3}](I) catalyzed partial reduction …
L={(ArHN)(ArN)− C= N− C=(NAr)(NHAr); Ar= 2, 6‐Et2‐C6H3}](I) catalyzed partial reduction …
CO2-Based Polycarbonates through Ring-Opening Polymerization of Cyclic Carbonates Promoted by a NHC-Based Zinc Complex
A backbone-substituted N-heterocyclic carbene (NHC) zinc complex, in combination with
alcohol initiators, has been shown to be an effective catalyst for the ring-opening …
alcohol initiators, has been shown to be an effective catalyst for the ring-opening …
Zinc hydride-catalyzed hydrofuntionalization of ketones
Three new dimeric bis-guanidinate zinc (II) alkyl, halide, and hydride complexes [LZnEt] 2
(1),[LZnI] 2 (2) and [LZnH] 2 (3) were prepared. Compound 3 was successfully employed for …
(1),[LZnI] 2 (2) and [LZnH] 2 (3) were prepared. Compound 3 was successfully employed for …
Luminescent Quantum Dots Stabilized by N-Heterocyclic Carbene Polymer Ligands
We have tested the ability of N-heterocyclic carbene (NHC)-modified ligands to coordinate
and stabilize luminescent CdSe–ZnS core–shell quantum dot (QD) dispersions in …
and stabilize luminescent CdSe–ZnS core–shell quantum dot (QD) dispersions in …
AN‐Heterocyclic Carbene‐Supported Zinc Catalyst for the 1, 2‐Regioselective Hydroboration of N‐Heteroarenes
A fluorenyl‐tethered N‐heterocyclic carbene LH (LH=[(Flu) H−(CH2) 2− NHCDipp]) and its
monoanionic version L− are explored in complexation with zinc towards the hydroboration of …
monoanionic version L− are explored in complexation with zinc towards the hydroboration of …
Synthesis, Structural Characterization, and Phosphorescence Properties of Trigonal Zn (II) Carbene Complexes
The sterically demanding N-heterocyclic carbene ITr (N, N′-bis (triphenylmethyl)
imidazolylidene) was employed for the preparation of novel trigonal zinc (II) complexes of …
imidazolylidene) was employed for the preparation of novel trigonal zinc (II) complexes of …