Tropospheric OH and HO 2 radicals: field measurements and model comparisons

D Stone, LK Whalley, DE Heard - Chemical Society Reviews, 2012 - pubs.rsc.org
The hydroxyl radical, OH, initiates the removal of the majority of trace gases in the
atmosphere, and together with the closely coupled species, the hydroperoxy radical, HO2, is …

Extensive field evidence for the release of HONO from the photolysis of nitrate aerosols

ST Andersen, LJ Carpenter, C Reed, JD Lee… - Science …, 2023 - science.org
Particulate nitrate (pNO 3−) has long been considered a permanent sink for NO x (NO and
NO2), removing a gaseous pollutant that is central to air quality and that influences the …

Intercomparison of MAX-DOAS vertical profile retrieval algorithms: studies on field data from the CINDI-2 campaign

JL Tirpitz, U Frieß, F Hendrick, C Alberti… - Atmospheric …, 2020 - amt.copernicus.org
Multi-A**s Differential Optical Absorption Spectroscopy (MAX-DOAS) is a well-established
ground-based measurement technique for the detection of aerosols and trace gases …

Design of a new multi-phase experimental simulation chamber for atmospheric photosmog, aerosol and cloud chemistry research

J Wang, JF Doussin, S Perrier… - Atmospheric …, 2011 - amt.copernicus.org
A new simulation chamber has been built at the Interuniversitary Laboratory of Atmospheric
Systems (LISA). The CESAM chamber (French acronym for Experimental Multiphasic …

Computational studies of the isomerization and hydration reactions of acetaldehyde oxide and methyl vinyl carbonyl oxide

KT Kuwata, MR Hermes, MJ Carlson… - The Journal of Physical …, 2010 - ACS Publications
Alkene ozonolysis is a major source of hydroxyl radical (• OH), the most important oxidant in
the troposphere. Previous experimental and computational work suggests that for many …

Review of Smog Chamber Experiments for Secondary Organic Aerosol Formation

H Kim, D Kang, HY Jung, J Jeon, JY Lee - Atmosphere, 2024 - mdpi.com
In this study, we reviewed smog chamber systems and methodologies used in secondary
organic aerosol (SOA) formation studies. Many important chambers across the world have …

Perspective on mechanism development and structure‐activity relationships for gas‐phase atmospheric chemistry

L Vereecken, B Aumont, I Barnes… - … journal of chemical …, 2018 - Wiley Online Library
This perspective gives our views on general aspects and future directions of gas‐phase
atmospheric chemical kinetic mechanism development, emphasizing on the work needed …

Direct measurements of OH and other product yields from the HO2  + CH3C(O)O2 reaction

FAF Winiberg, TJ Dillon, SC Orr… - Atmospheric …, 2016 - acp.copernicus.org
The reaction CH 3 C (O) O 2+ HO 2→ CH 3 C (O) OOH+ O 2 (Reaction R5a), CH 3 C (O)
OH+ O 3 (Reaction R5b), CH 3+ CO 2+ OH+ O 2 (Reaction R5c) was studied in a series of …

Measurements of OH and HO2 yields from the gas phase ozonolysis of isoprene

TL Malkin, A Goddard, DE Heard… - … Chemistry and Physics, 2010 - acp.copernicus.org
The reactions of ozone with alkenes are an important source of hydroxyl (OH) radicals;
however, quantification of their importance is hindered by uncertainties in the absolute OH …

An intercomparison of HO2 measurements by fluorescence assay by gas expansion and cavity ring-down spectroscopy within HIRAC (Highly Instrumented Reactor …

L Onel, A Brennan, M Gianella, G Ronnie… - Atmospheric …, 2017 - amt.copernicus.org
The HO 2 radical was monitored simultaneously using two independent techniques in the
Leeds HIRAC (Highly Instrumented Reactor for Atmospheric Chemistry) atmospheric …