Polyoxometalates-based functional materials in chemiresistive gas sensors and electrochemical sensors

L Chen, J Geng, Z Guo, XJ Huang - TrAC Trends in Analytical Chemistry, 2023 - Elsevier
The construction of chemiresistive gas sensors and electrochemical sensors for various
application scenarios has greatly facilitated human progress and altered the course of …

Supported polyoxometalates as emerging nanohybrid materials for photochemical and photoelectrochemical water splitting

I Ullah, A Munir, A Haider, N Ullah, I Hussain - Nanophotonics, 2021 - degruyter.com
Sunlight and water are among the most plentiful and sustainable resources of energy.
Natural photosystem II in the plants uses these resources in ecofriendly manner for the …

Metallodrug Profiling against SARS‐CoV‐2 Target Proteins Identifies Highly Potent Inhibitors of the S/ACE2 interaction and the Papain‐like Protease PLpro

M Gil‐Moles, S Türck, U Basu… - … A European Journal, 2021 - Wiley Online Library
The global spread of the severe acute respiratory syndrome coronavirus 2 (SARS‐CoV‐2)
has called for an urgent need for dedicated antiviral therapeutics. Metal complexes are …

PtIV-Containing Hexaplatinate(II) [PtIVPtII6O6(AsO2(CH3)2)6]2– and Hexapalladate(II) [PtIVPdII6O6(AsO2(CH3)2)6]2–

J Zhang, S Bhattacharya, BE Khsara, T Nisar… - Inorganic …, 2023 - ACS Publications
The first PtIV-containing discrete polyoxoplatinate (II)[PtIVPtII6O6 (AsO2 (CH3) 2) 6] 2–(Pt 7)
and polyoxopalladate (II)[PtIVPdII6O6 (AsO2 (CH3) 2) 6] 2–(PtPd 6) have been prepared …

Silver‐Templated γ‐Keggin Alkyltin‐Oxo Cluster: Electronic Structure and Optical Limiting Effect

Y Zhu, Z Wang, D Li, YD Zhu, QH Li… - Angewandte Chemie …, 2022 - Wiley Online Library
As one of the most representative polyoxometalate (POM) structures, Keggin clusters have
attracted considerable attention. Nevertheless, the noble‐metal‐templated Keggin structure …

Discrete, Cationic Palladium (II)‐Oxo Clusters via f‐Metal Ion Incorporation and their Macrocyclic Host‐Guest Interactions with Sulfonatocalixarenes

S Bhattacharya, A Barba‐Bon… - Angewandte Chemie …, 2022 - Wiley Online Library
We report on the discovery of the first two examples of cationic palladium (II)‐oxo clusters
(POCs) containing f‐metal ions,[PdII6O12M8 {(CH3) 2AsO2} 16 (H2O) 8] 4+(M= CeIV, ThIV) …

Stepwise assembly and reversible structural transformation of ligated titanium coated bismuth-oxo cores: shell morphology engineering for enhanced chemical fixation …

QR Ding, Y Yu, C Cao, J Zhang, L Zhang - Chemical Science, 2022 - pubs.rsc.org
Herein, we report the stepwise assembly and reversible transformation of atomically precise
ligated titanium coated bismuth-oxide core nanostructures. The soluble and stable …

Gallium (III)-and Thallium (III)-Encapsulated Polyoxopalladates: Synthesis, Structure, Multinuclear NMR, and Biological Activity Studies

T Ma, X Ma, Z Lin, J Zhang, P Yang, T Csupász… - Inorganic …, 2023 - ACS Publications
Three gallium (III)-and thallium (III)-containing polyoxopalladates (POPs) have been
synthesized and structurally characterized in the solid state and in solution, namely, the …

Mixed noble metal–oxo clusters: platinum (iv)–gold (iii) oxoanion [Pt IV 2 Au III 3 O 6 ((CH 3) 2 AsO 2) 6]−

J Zhang, S Bhattacharya, AB Müller, L Kiss… - Chemical …, 2023 - pubs.rsc.org
The first discrete mixed platinum (IV)–gold (III) oxoanion [PtIV2AuIII3O6 ((CH3) 2AsO2)
6]−(1) was synthesized by reaction of H2Pt (OH) 6 with H [AuCl4] in a simple one-pot …

Water‐soluble Self‐assembled {Pd84}Ac Polyoxopalladate Nano‐wheel as a Supramolecular Host

ZL Sinclair, NL Bell, JR Bame… - Angewandte Chemie …, 2023 - Wiley Online Library
Polyoxopalladates (POPs) are a class of self‐assembling palladium‐oxide clusters that span
a variety of sizes, shapes and compositions. The largest of this family,{Pd84} Ac, is …