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Through-space conjugation: a thriving alternative for optoelectronic materials
Efficient electronic coupling is the key to constructing optoelectronic functional π systems.
Generally, the delocalization of π electrons must comply with the framework constructed by …
Generally, the delocalization of π electrons must comply with the framework constructed by …
Multi‐layer π‐stacked molecules as efficient thermally activated delayed fluorescence emitters
Multi‐layer π‐stacked emitters based on spatially confined donor/acceptor/donor (D/A/D)
patterns have been developed to achieve high‐efficiency thermally activated delayed …
patterns have been developed to achieve high‐efficiency thermally activated delayed …
Thienylvinylenethienyl and naphthalene core substituted with triphenylamines—Highly efficient hole transporting materials and their comparative study for inverted …
In this report, two simple cost efficient solution processable small molecular hole
transporting materials (HTMs) are synthesized and used successfully in inverted perovskite …
transporting materials (HTMs) are synthesized and used successfully in inverted perovskite …
Tuning Electron Transfer Coupling and Exchange Interaction in Bis-triarylamine Radical Cations and Dications by Bridge Electron Density
L Euringer, M Holzapfel, I Krummenacher… - Journal of the …, 2024 - ACS Publications
The influence of the electron density of a bridge connecting two redox centers on both the
intervalence hole transfer and the magnetic superexchange was investigated in a series of …
intervalence hole transfer and the magnetic superexchange was investigated in a series of …
π-Stacked thermally activated delayed fluorescence emitters with alkyl chain modulation
Molecules bearing separate π-electron donor (D) and acceptor (A) groups that undergo face-
to-face D/A interactions have been utilized to develop thermally activated delayed …
to-face D/A interactions have been utilized to develop thermally activated delayed …
Hole Transfer Processes in meta- and para-Conjugated Mixed Valence Compounds: Unforeseen Effects of Bridge Substituents and Solvent Dynamics
J Schäfer, M Holzapfel, B Mladenova… - Journal of the …, 2017 - ACS Publications
To address the question whether donor substituents can be utilized to accelerate the hole
transfer (HT) between redox sites attached in para-or in meta-positions to a central benzene …
transfer (HT) between redox sites attached in para-or in meta-positions to a central benzene …
Through-space conjugation: An effective strategy for stabilizing intramolecular charge-transfer states
Intramolecular charge transfer (ICT) has significant impacts on organic optoelectronic
materials, photochemistry, biotechnology, and so on. However, it is hard to stabilize the ICT …
materials, photochemistry, biotechnology, and so on. However, it is hard to stabilize the ICT …
Remarkable influence of 'phane effect'on the excited-state properties of cofacially oriented coumarins
A comprehensive investigation of the photophysics of a cofacially oriented bis-coumarin
based on naphthalene, ie, Cou-Nap, designed and synthesized to examine the influence of …
based on naphthalene, ie, Cou-Nap, designed and synthesized to examine the influence of …
Electron storage system based on a two-way inversion of redox potentials
Molecular-level multielectron handling toward electrical storage is a worthwhile approach to
solar energy harvesting. Here, a strategy which uses chemical bonds as electron reservoirs …
solar energy harvesting. Here, a strategy which uses chemical bonds as electron reservoirs …
Fine tuning of electron transfer and spin chemistry parameters in triarylamine–bridge–naphthalene diimide dyads by bridge substituents
J Schäfer, M Holzapfel, A Schmiedel… - Physical Chemistry …, 2018 - pubs.rsc.org
The photoinduced charge separation and charge recombination in a set of four molecular
dyads consisting of a triarylamine donor and a naphthalene diimide acceptor were …
dyads consisting of a triarylamine donor and a naphthalene diimide acceptor were …