Catalysis as an enabling science for sustainable polymers

X Zhang, M Fevre, GO Jones, RM Waymouth - Chemical reviews, 2018 - ACS Publications
The replacement of current petroleum-based plastics with sustainable alternatives is a
crucial but formidable challenge for the modern society. Catalysis presents an enabling tool …

Alternative monomers based on lignocellulose and their use for polymer production

I Delidovich, PJC Hausoul, L Deng… - Chemical …, 2016 - ACS Publications
Polymeric materials play a key role in modern industry. Owing to outstanding and very
versatile properties of polymers, they have rather quickly occupied the great niche of …

Exploiting multimetallic cooperativity in the ring-opening polymerization of cyclic esters and ethers

U Yolsal, PJ Shaw, PA Lowy, R Chambenahalli… - ACS …, 2024 - ACS Publications
The use of multimetallic complexes is a rapidly advancing route to enhance catalyst
performance in the ring-opening polymerization of cyclic esters and ethers. Multimetallic …

Controlled ring-opening polymerization of lactide and glycolide

O Dechy-Cabaret, B Martin-Vaca… - Chemical reviews, 2004 - ACS Publications
Synthetic petrochemical-based polymers have had a tremendous industrial impact since the
1940s. Despite the numerous advantages of these materials, two major drawbacks remain …

Stereocontrolled ring-opening polymerisation of lactide

MJ Stanford, AP Dove - Chemical Society Reviews, 2010 - pubs.rsc.org
The important advances and current trends in the stereocontrolled ring-opening
polymerisation of lactide are discussed in this tutorial review. Microstructures, structural …

Stereocontrolled ring-opening polymerization of cyclic esters: synthesis of new polyester microstructures

CM Thomas - Chemical Society Reviews, 2010 - pubs.rsc.org
Synthesis of aliphatic polyesters has been studied intensively due to their biocompatible and
biodegradable properties and their potential applications in medical and agricultural fields …

Polylactic acid (PLA): Research, development and industrialization

X Pang, X Zhuang, Z Tang, X Chen - Biotechnology journal, 2010 - Wiley Online Library
Polylactide (PLA) is a biodegradable, aliphatic polyester derived from lactic acid. It has
similar mechanical properties to polyethylene terephthalate, but has a significantly lower …

Synthesis of biodegradable polymers from renewable resources

MJL Tschan, E Brulé, P Haquette, CM Thomas - Polymer Chemistry, 2012 - pubs.rsc.org
The vast majority of commodity materials are obtained from fossil fuels. However, many
studies predict that all fossil resources will be depleted within a few centuries. Biomass …

Biocompatible initiators for lactide polymerization

RH Platel, LM Hodgson, CK Williams - Polymer Reviews, 2008 - Taylor & Francis
The review summarizes recent developments in the preparation and use of new initiators for
the ring opening polymerization of lactide. The review compares different classes of initiator …

Metal-catalyzed immortal ring-opening polymerization of lactones, lactides and cyclic carbonates

N Ajellal, JF Carpentier, C Guillaume… - Dalton …, 2010 - pubs.rsc.org
This Perspective article summarizes efforts paid in our group to develop efficient metal-
based catalysts for the immortal ring-opening polymerization (iROP) of cyclic esters in the …