Water structures on acidic zeolites and their roles in catalysis

Q Liu, JA van Bokhoven - Chemical Society Reviews, 2024 - pubs.rsc.org
The local reaction environment of catalytic active sites can be manipulated to modify the
kinetics and thermodynamic properties of heterogeneous catalysis. Because of the unique …

Ab initio simulations of water/metal interfaces

A Groß, S Sakong - Chemical reviews, 2022 - ACS Publications
Structures and processes at water/metal interfaces play an important technological role in
electrochemical energy conversion and storage, photoconversion, sensors, and corrosion …

Selective Hydrodeoxygenation of Aromatics to Cyclohexanols over Ru Single Atoms Supported on CeO2

K Zhang, Q Meng, H Wu, J Yan, X Mei… - Journal of the …, 2022 - ACS Publications
Cyclohexanols are widely used chemicals, which are mainly produced by oxidation of fossil
feedstocks. Selective hydrodeoxygenation of lignin derivatives has great potential for …

Electrocatalytic hydrogenation of biomass-derived organics: a review

SA Akhade, N Singh, OY Gutiérrez… - Chemical …, 2020 - ACS Publications
Sustainable energy generation calls for a shift away from centralized, high-temperature,
energy-intensive processes to decentralized, low-temperature conversions that can be …

Elucidating the roles of electric fields in catalysis: a perspective

F Che, JT Gray, S Ha, N Kruse, SL Scott… - ACS …, 2018 - ACS Publications
This Perspective illustrates how the presence of internal and external electric fields can
affect catalytic activity and selectivity, with a focus on heterogeneous catalysts. Specifically …

Solvent-mediated charge separation drives alternative hydrogenation path of furanics in liquid water

Z Zhao, R Bababrik, W Xue, Y Li, NM Briggs… - Nature Catalysis, 2019 - nature.com
Compared to the vapour phase, liquid-phase heterogeneous catalysis provides additional
degrees of freedom for reaction engineering, but the multifaceted solvent effects complicate …

Water-mediated heterogeneously catalyzed reactions

G Li, B Wang, DE Resasco - Acs Catalysis, 2019 - ACS Publications
Nature takes advantage of the pervasive presence of water to control many enzymatic
reactions by utilizing the unique properties of water, which in turn help regulating reaction …

Progress in accurate chemical kinetic modeling, simulations, and parameter estimation for heterogeneous catalysis

S Matera, WF Schneider, A Heyden, A Savara - Acs Catalysis, 2019 - ACS Publications
Chemical kinetic modeling in heterogeneous catalysis is advancing in its ability to provide
qualitatively or even quantitatively accurate prediction of real-world behavior because of …

Influence of solvent structure and hydrogen bonding on catalysis at solid–liquid interfaces

DS Potts, DT Bregante, JS Adams, C Torres… - Chemical Society …, 2021 - pubs.rsc.org
Solvent molecules interact with reactive species and alter the rates and selectivities of
catalytic reactions by orders of magnitude. Specifically, solvent molecules can modify the …

Boosting catalytic selectivity through a precise spatial control of catalysts at pickering droplet interfaces

H Zou, H Shi, S Hao, Y Hao, J Yang… - Journal of the …, 2023 - ACS Publications
Exploration of new methodologies to tune catalytic selectivity is a long-sought goal in
catalytic community. In this work, oil–water interfaces of Pickering emulsions are developed …