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The chemistry of [M3 (CO) 10 (μ-dppm)](M= Ru, Os): Activating and maintaining the trinuclear core
SE Kabir, G Hogarth - Coordination Chemistry Reviews, 2009 - Elsevier
Ruthenium and osmium dodecacarbonyls, M3 (CO) 12 (M= Ru, Os), find extensive use as
precursors towards a range of low-valent ruthenium and osmium compounds, being …
precursors towards a range of low-valent ruthenium and osmium compounds, being …
Thermolysis of Ru3 (CO) 10 (µ-dppp): A new Ru4-cluster derived from 1, 3-bis (diphenylphosphino) propane
The reaction of Ru 3 (CO) 12 and dppp [dppp= 1, 3-bis (diphenylphosphino) propane/Ph 2 P
(CH 2) 3 PPh 2] in the presence of benzophenone ketyl radical anion afforded [Ru 3 (CO) …
(CH 2) 3 PPh 2] in the presence of benzophenone ketyl radical anion afforded [Ru 3 (CO) …
Chelate and Bridge Diphosphine Isomerization: Triosmium and Triruthenium Clusters Containing 1, 1 '-Bis (diphenylphosphino) ferrocene (dppf)
The coordination mode of dppf {dppf= 1, 1 '-bis (diphenylphosphino) ferrocene} at triosmium
and triruthenium carbonyl clusters has been studied. Heating [Os3 (CO) 12] with dppf in the …
and triruthenium carbonyl clusters has been studied. Heating [Os3 (CO) 12] with dppf in the …
Reactions of Ru3 (CO) 12 with 1, 5-bis (diphenylphosphino) pentane: Synthesis, characterization, crystal structure, Hirshfeld surface and QTAIM Analysis of Ru3 (CO) …
Abstract Reactions of Ru 3 (CO) 12 with 1, 5-bis (diphenylphosphino) pentane (dpppe) in
THF induced by sodium benzophenone ketyl radical anion, resulted in the expected metal …
THF induced by sodium benzophenone ketyl radical anion, resulted in the expected metal …
Synthesis, structures and reactivity of bis (diphenylphosphino)-methane (dppm)-substituted selenido osmium carbonyl clusters
SE Kabir, S Pervin, NC Sarker, A Yesmin… - Journal of …, 2003 - Elsevier
The unsaturated cluster [(μ-H) Os3 (CO) 8 {Ph2PCH2P (Ph) C6H4}](2) reacts with elemental
selenium at 110° C to give two triosmium clusters [Os3 (CO) 7 (μ3-Se) 2 (μ-dppm)](3),[Os3 …
selenium at 110° C to give two triosmium clusters [Os3 (CO) 7 (μ3-Se) 2 (μ-dppm)](3),[Os3 …
X-ray structure of [Os3 (CO) 10 (μ-Ph2PCH2PPh2)]
KA Azam, MB Hursthouse, SE Kabir, KMA Malik… - Journal of chemical …, 1999 - Springer
Abstract Decacarbonyl-μ-bis (diphenylphosphino) methane triosmium crystallizes in the
monoclinic space group P 2 1/c with a= 24.422 (5), b= 12.381 (2), c= 24.788 (5) Å, β= 103.69 …
monoclinic space group P 2 1/c with a= 24.422 (5), b= 12.381 (2), c= 24.788 (5) Å, β= 103.69 …
A comparative study of the reactivity of unsaturated triosmium clusters [Os3 (CO) 8 {μ3-Ph2PCH2P (Ph) C6H4}(μ-H)] and [Os3 (CO) 9 {μ3-η2-C7H3 (2-Me) NS}(μ-H)] …
Treatment of unsaturated [Os3 (CO) 8 {μ3-Ph2PCH2P (Ph) C6H4}(μ-H)](2) with tBuNC at
room temperature gives [Os3 (CO) 8 (CNBut)){μ3-Ph2PCH2P (Ph) C6H4}(μ-H)](3) which on …
room temperature gives [Os3 (CO) 8 (CNBut)){μ3-Ph2PCH2P (Ph) C6H4}(μ-H)](3) which on …
Synthesis, structure and reactivity of triosmium clusters derived from the reactions of [Os 3 (CO) 10 (Á-dppm)](dppmá= áPh 2 PCH 2 PPh 2) and [Os 3 (Á-H)(CO) 8 {Ph …
KA Azam, MB Hursthouse, M áRafiqul Islam… - Journal of the …, 1998 - pubs.rsc.org
The reaction of [Os3 (CO) 10 (µ-dppm)] 1 with diphenylphosphine in refluxing toluene led to
the substituted cluster [Os3 (CO) 9 (µ-dppm)(PHPh2)] 3 and the phosphido-bridged …
the substituted cluster [Os3 (CO) 9 (µ-dppm)(PHPh2)] 3 and the phosphido-bridged …
Thermolysis of Ru3 (CO) 10 (dppb): Activation of CH and PPh bonds in PPh2P (CH2) 4PPh2 (dppb= 1, 4-bis (diphenylphosphino) butane)
The thermolysis reaction of Ru 3 (CO) 10 (dppb) 1 for 4 h in refluxing toluene resulted in the
formation of Ru 3 (CO) 7 (μ 3-C 6 H 4)(μ-PPh 2){μ-PPhBu n} 2, Ru 5 (CO) 14 (μ 4-PPh){PPh …
formation of Ru 3 (CO) 7 (μ 3-C 6 H 4)(μ-PPh 2){μ-PPhBu n} 2, Ru 5 (CO) 14 (μ 4-PPh){PPh …
Structural and nuclear magnetic resonance studies of triosmium and triruthenium carbonyl cluster derivatives containing pentaphenylcyclopentaphosphane
HG Ang, SG Ang, Q Zhang - Journal of the Chemical Society, Dalton …, 1996 - pubs.rsc.org
The reaction of pentaphenylcyclopentaphosphane (PPh) 5 with [Os3 (CO) 10 (NCMe) 2] in
1: 1 molar ratio afforded a pair of inversion isomers, 1 and 2, with the molecular formula [Os3 …
1: 1 molar ratio afforded a pair of inversion isomers, 1 and 2, with the molecular formula [Os3 …