Polyoxometalates (POMs) are a subset of metal oxides that represent a diverse range of
molecular clusters with an almost unmatched range of physical properties and the ability to …

Polyoxometalates are clusters of metal-oxide units, comprising a large diversity of nanoscale
structures, and have many common building blocks; in fact polyoxometalate clusters are …

During the past decade, research into transition-metal-substituted polyoxometalate self-
assembly has been greatly developed. This review summarizes the conventional solution …

With the rapid development of science and technology and the trend of multidisciplinary
pervasion, POM-based TM–RE heterometallic chemistry (POM= polyoxometalate, TM …

This critical review surveys the 3d substituted magnetic polyoxotungstate (POT) molecular
compounds reported these last ten years, illustrating the huge variety of topologies that …

Abstract A protein‐sized (ca. 4.2× 4.2× 3.6 nm3) non‐biologically derived molecule
{Nb288O768 (OH) 48 (CO3) 12}(Nb288) containing up to 288 niobium atoms has been …

The assembly of gigantic heterometallic metal clusters remains a great challenge for
synthetic chemistry. Herein, based on the slow release strategy of lanthanide ions and in situ …

The research on heterometallic 3d-4f polyoxometalates has made immense progress over
the last decade with a larger number of structures being reported every year until the present …

A giant tetrahedral heterometallic polyoxometalate (POM)[Dy30Co8Ge12W108O408 (OH)
42 (OH2) 30] 56−, which shows single‐molecule magnet (SMM) behavior, is described. This …

The stabilization and immobilization of polyoxometalates (POMs) through the formation of
POM-containing coordination polymers is one of the more attractive areas of supramolecular …