Pendant amines play an invaluable role in chemical reactivity, especially for molecular
catalysts based on earth-abundant metals. As inspired by [FeFe]-hydrogenases, which …

Transition metal hydride complexes are usually amphoteric, not only acting as hydride
donors, but also as Brønsted–Lowry acids. A simple additive ligand acidity constant …

Proton transfer is crucial for electrocatalysis. Accumulating cations at electrochemical
interfaces can alter the proton transfer rate and then tune electrocatalytic performance …

The cleavage of C–O bonds in phenol, catechol, and guaiacol has been explored with mono-
and dual-functional catalysts containing Ni and/or HZSM-5 in the aqueous phase. The …

Condensation of fac-Re (5, 6-diamino-1, 10-phenanthroline)(CO) 3Cl to o-quinone edge
defects on graphitic carbon surfaces generates graphite-conjugated rhenium (GCC-Re) …

The dihydrogen bond an interaction between a transition-metal or main-group hydride (M
H) and a protic hydrogen moiety (H X) is arguably the most intriguing type of hydrogen …

We demonstrate the solvent-free synthesis of a covalent organic framework (COF)
containing 5, 10, 15, 20-tetra-(4-aminophenyl) porphyrin Fe (III) chloride (FeTAPPCl) and 2 …

Ab initio molecular dynamics simulations combined with enhanced sampling techniques are
becoming widespread methods to investigate chemical phenomena in catalytic systems …

Generation of hydrogen by reduction of two protons by two electrons can be catalysed by
molecular electrocatalysts. Determination of the thermodynamic driving force for elimination …

Conspectus The electrochemical CO2 reduction reaction (CO2RR) is an attractive method
for capturing intermittent renewable energy sources in chemical bonds, and converting …