Transition metal-catalyzed direct functionalization of C–H bonds is one of the key emerging
strategies that is currently attracting tremendous attention with the aim to provide alternative …

The use of directing groups has proven to be a successful strategy to enhance reactivity and
control selectivity in C–H functionalization reactions. In the past decade, a multitude of new …

Synthetic organic chemistry has witnessed a plethora of functionalization and
defunctionalization strategies. In this regard, C− H functionalization has been at the forefront …

Six-membered heterocycles containing one phosphorus and one nitrogen atom, known as
azaphosphinines, have existed in the shadows of their single heteroatom-containing …

Conspectus Given the important influence of phosphine ligands in transition metal-catalyzed
reactions, chemists have searched for straightforward and efficient methodologies for the …

Compounds with stereogenic phosphorus atoms are frequently used as ligands for transition‐
metal as well as organocatalysts. A direct catalytic enantioselective method for the synthesis …

The Rh (III)-catalyzed annulative C–H functionalization of arenes with sulfoxonium ylides
has been realized. Arenes assisted by diverse nucleophilic directing groups are viable …

Abstract [Cp* RhIII]‐catalyzed C H activation of arenes assisted by an oxidizing N O or
N N directing group has allowed the construction of a number of hetercycles. In contrast, a …

meta-Hydroxylated cores are ubiquitous in natural products. Herein, we disclose the first
template assisted meta-hydroxylation reaction. Experimental and in silico studies helped us …

Group 10 metal catalysts have shown much promise for the copolymerization of nonpolar
with polar alkenes to directly generate functional materials, but access to high copolymer …