Power of infrared and Raman spectroscopies to characterize metal-organic frameworks and investigate their interaction with guest molecules

KI Hadjiivanov, DA Panayotov, MY Mihaylov… - Chemical …, 2020 - ACS Publications
The variety of functionalities and porous structures inherent to metal-organic frameworks
(MOFs) together with the facile tunability of their properties makes these materials suitable …

Electrically conductive metal–organic frameworks

LS **e, G Skorupskii, M Dinca - Chemical reviews, 2020 - ACS Publications
Metal–organic frameworks (MOFs) are intrinsically porous extended solids formed by
coordination bonding between organic ligands and metal ions or clusters. High electrical …

ChatGPT chemistry assistant for text mining and the prediction of MOF synthesis

Z Zheng, O Zhang, C Borgs, JT Chayes… - Journal of the …, 2023 - ACS Publications
We use prompt engineering to guide ChatGPT in the automation of text mining of metal–
organic framework (MOF) synthesis conditions from diverse formats and styles of the …

Coordinatively unsaturated metal sites (open metal sites) in metal–organic frameworks: design and applications

Ü Kökçam-Demir, A Goldman, L Esrafili… - Chemical Society …, 2020 - pubs.rsc.org
Metal–organic frameworks (MOFs) can contain open metal sites (OMS) or coordinatively
unsaturated sites (CUS) or open coordination sites (OCS) when vacant Lewis acid sites on …

Porous metal–organic frameworks for hydrogen storage

D Zhao, X Wang, L Yue, Y He, B Chen - Chemical Communications, 2022 - pubs.rsc.org
The high gravimetric energy density and environmental benefits place hydrogen as a
promising alternative to the widely used fossil fuels, which is however impeded by the lack of …

Microporous metal-organic framework materials for gas separation

RB Lin, S **ang, W Zhou, B Chen - Chem, 2020 - cell.com
Gas separation is a very important industrial process for manufacturing chemicals, fuels,
plastics, and polymers but is also energy intensive through the traditional cryogenic …

A decade of UiO-66 research: a historic review of dynamic structure, synthesis mechanisms, and characterization techniques of an archetypal metal–organic …

J Winarta, B Shan, SM Mcintyre, L Ye… - Crystal Growth & …, 2019 - ACS Publications
UiO-66 is an archetypal metal–organic framework (MOF) with a very high surface area as
well as high thermal stability. It is found that the stability can be attributed to the metal oxide …

Metal–organic framework magnets

AE Thorarinsdottir, TD Harris - Chemical reviews, 2020 - ACS Publications
Metal–organic frameworks represent the ultimate chemical platform on which to develop a
new generation of designer magnets. In contrast to the inorganic solids that have dominated …

Ethane/ethylene separation in a metal-organic framework with iron-peroxo sites

L Li, RB Lin, R Krishna, H Li, S **ang, H Wu, J Li… - Science, 2018 - science.org
The separation of ethane from its corresponding ethylene is an important, challenging, and
energy-intensive process in the chemical industry. Here we report a microporous metal …

Recent advances in gas storage and separation using metal–organic frameworks

H Li, K Wang, Y Sun, CT Lollar, J Li, HC Zhou - Materials Today, 2018 - Elsevier
Gas storage and separation are closely associated with the alleviation of greenhouse effect,
the widespread use of clean energy, the control of toxic gases, and various other aspects in …