Peptide-based supramolecular systems chemistry
Peptide-based supramolecular systems chemistry seeks to mimic the ability of life forms to
use conserved sets of building blocks and chemical reactions to achieve a bewildering array …
use conserved sets of building blocks and chemical reactions to achieve a bewildering array …
Dynamic and reconfigurable materials from reversible network interactions
Polymer materials provide solutions to some of the most pressing environmental,
manufacturing and health-care challenges. Traditional thermoplastic and thermoset …
manufacturing and health-care challenges. Traditional thermoplastic and thermoset …
Stimuli responsive dynamic transformations in supramolecular gels
Supramolecular gels are formed by the self-assembly of small molecules under the
influence of various non-covalent interactions. As the interactions are individually weak and …
influence of various non-covalent interactions. As the interactions are individually weak and …
Peptide-based coacervates as biomimetic protocells
Coacervates are condensed liquid-like droplets formed by liquid–liquid phase separation of
molecules through multiple weak associative interactions. In recent years it has emerged …
molecules through multiple weak associative interactions. In recent years it has emerged …
Chemically fueled self‐assembly in biology and chemistry
Life is a non‐equilibrium state of matter maintained at the expense of energy. Nature uses
predominantly chemical energy stored in thermodynamically activated, but kinetically stable …
predominantly chemical energy stored in thermodynamically activated, but kinetically stable …
Autonomous fuelled directional rotation about a covalent single bond
Biology operates through autonomous chemically fuelled molecular machinery, including
rotary motors such as adenosine triphosphate synthase and the bacterial flagellar motor …
rotary motors such as adenosine triphosphate synthase and the bacterial flagellar motor …
Chemical fuels for molecular machinery
Chemical reaction networks that transform out-of-equilibrium 'fuel'to 'waste'are the engines
that power the biomolecular machinery of the cell. Inspired by such systems, autonomous …
that power the biomolecular machinery of the cell. Inspired by such systems, autonomous …
Insights into chemically fueled supramolecular polymers
Supramolecular polymerization can be controlled in space and time by chemical fuels. A
nonassembled monomer is activated by the fuel and subsequently self-assembles into a …
nonassembled monomer is activated by the fuel and subsequently self-assembles into a …
Revising complex supramolecular polymerization under kinetic and thermodynamic control
J Matern, Y Dorca, L Sánchez… - Angewandte Chemie …, 2019 - Wiley Online Library
Pathway complexity, hierarchical organization, out of equilibrium, and metastable or
kinetically trapped species are common terms widely used in recent, high‐quality …
kinetically trapped species are common terms widely used in recent, high‐quality …
Energy consumption in chemical fuel-driven self-assembly
Nature extensively exploits high-energy transient self-assembly structures that are able to
perform work through a dissipative process. Often, self-assembly relies on the use of …
perform work through a dissipative process. Often, self-assembly relies on the use of …