Peptide-based supramolecular systems chemistry

F Sheehan, D Sementa, A Jain, M Kumar… - Chemical …, 2021 - ACS Publications
Peptide-based supramolecular systems chemistry seeks to mimic the ability of life forms to
use conserved sets of building blocks and chemical reactions to achieve a bewildering array …

Dynamic and reconfigurable materials from reversible network interactions

MJ Webber, MW Tibbitt - Nature Reviews Materials, 2022 - nature.com
Polymer materials provide solutions to some of the most pressing environmental,
manufacturing and health-care challenges. Traditional thermoplastic and thermoset …

Stimuli responsive dynamic transformations in supramolecular gels

S Panja, DJ Adams - Chemical Society Reviews, 2021 - pubs.rsc.org
Supramolecular gels are formed by the self-assembly of small molecules under the
influence of various non-covalent interactions. As the interactions are individually weak and …

Peptide-based coacervates as biomimetic protocells

M Abbas, WP Lipiński, J Wang, E Spruijt - Chemical Society Reviews, 2021 - pubs.rsc.org
Coacervates are condensed liquid-like droplets formed by liquid–liquid phase separation of
molecules through multiple weak associative interactions. In recent years it has emerged …

Chemically fueled self‐assembly in biology and chemistry

K Das, L Gabrielli, LJ Prins - Angewandte Chemie International …, 2021 - Wiley Online Library
Life is a non‐equilibrium state of matter maintained at the expense of energy. Nature uses
predominantly chemical energy stored in thermodynamically activated, but kinetically stable …

Autonomous fuelled directional rotation about a covalent single bond

S Borsley, E Kreidt, DA Leigh, BMW Roberts - Nature, 2022 - nature.com
Biology operates through autonomous chemically fuelled molecular machinery, including
rotary motors such as adenosine triphosphate synthase and the bacterial flagellar motor …

Chemical fuels for molecular machinery

S Borsley, DA Leigh, BMW Roberts - Nature Chemistry, 2022 - nature.com
Chemical reaction networks that transform out-of-equilibrium 'fuel'to 'waste'are the engines
that power the biomolecular machinery of the cell. Inspired by such systems, autonomous …

Insights into chemically fueled supramolecular polymers

A Sharko, D Livitz, S De Piccoli, KJM Bishop… - Chemical …, 2022 - ACS Publications
Supramolecular polymerization can be controlled in space and time by chemical fuels. A
nonassembled monomer is activated by the fuel and subsequently self-assembles into a …

Revising complex supramolecular polymerization under kinetic and thermodynamic control

J Matern, Y Dorca, L Sánchez… - Angewandte Chemie …, 2019 - Wiley Online Library
Pathway complexity, hierarchical organization, out of equilibrium, and metastable or
kinetically trapped species are common terms widely used in recent, high‐quality …

Energy consumption in chemical fuel-driven self-assembly

G Ragazzon, LJ Prins - Nature nanotechnology, 2018 - nature.com
Nature extensively exploits high-energy transient self-assembly structures that are able to
perform work through a dissipative process. Often, self-assembly relies on the use of …