Kinetics and Mechanism of Mn (II) catalyzed periodate oxidation of p-anisidine: Effect of pH

RD Kaushik, J Singh, M Manila, M Kaur… - Bulletin of Chemical …, 2014 - journal.bcrec.id
The stoichiometry for the initial part of the reaction, Mn (II) catalysed periodate oxidation of p-
anisidine (PMA), has been found to be 1 mol of PMA consuming 2 mol of periodate ion. The …

[PDF][PDF] Kinetics and Mechanism of MnII catalyzed periodate oxidation of o-anisidine

RD Kaushik, RM Agarwal, J Shing - Res. J. Pharm. Biol. Chem. Sci., 2014 - hakon-art.com
The kinetics of the periodate oxidation of o-anisidine (ANIS) in acetone-water medium has
been followed by monitoring the increase in the absorbance of reaction intermediate, C4 …

[PDF][PDF] Stopped flow kinetics and mechanistic study of periodate degradation of persist carcinogenic 2, 6 xylidine by Mn (II) catalyst

K Saini, RD Kaushik, J Singh - Rasayan Journal of Chemistry, 2022 - researchgate.net
The periodate oxidation of 2, 6 xylidine catalyzed by Mn (II) in a solution containing acetone
miscible in water was studied using stopped-flow kinetics. The reaction was progressed at …

[PDF][PDF] Mn II Catalyzed Oxidation of 2, 5-Xylidine by Periodate Ion–A Kinetic and Mechanistic Study

J Singh, RD Kaushik, O Singh, R Saini… - Acta Chim Pharm …, 2017 - academia.edu
The kinetics of the periodate oxidation of 2, 5-Xylidine (2, 5-XYL) in acetone-water medium
has been followed by monitoring the increase in the absorbance of reaction intermediate …

[PDF][PDF] Stopped flow kinetics of Mn II catalysed Periodate Oxidation of o-Anisidine–First Report on Stability constant of the ternary Intermediate complex formation

J Singh, RD Kaushik, O Singh, R Saini, E Kumari - academia.edu
This paper is the first report on kinetic study and evaluation of stability constant of ternary
complex forming in the MnII-catalysed periodate oxidation of o-Anisidine (OA) in acetone …

[PDF][PDF] EVALUATION OF KINETIC PARAMETERS FOR Mn II CATALYZED PERIODATE OXIDATION OF m-TOLUIDINE: A MECHANISTIC STUDY

J Singh - rasayanjournal.co.in
The reaction kinetics of oxidation of m-toluidine by periodate in the acetone-water medium in
the presence of MnII as catalyst was investigated systematically by detecting the change in …

EVALUATION OF KINETIC PARAMETERS FOR MnII CATALYZED PERIODATE OXIDATION OF m-TOLUIDINE: A MECHANISTIC STUDY.

RD Kaushik, MM Tiwari, M Chawla… - Rasayan Journal of …, 2019 - search.ebscohost.com
The reaction kinetics of oxidation of m-toluidine by periodate in the acetone-water medium in
the presence of MnII as catalyst was investigated systematically by detecting the change in …

[PDF][PDF] EVALUATION OF STABILITY CONSTANT OF TERNARY INTERMEDIATE COMPLEX FORMATION IN MnII CATALYSED PERIODATE OXIDATION OF 2, 5 …

RD Kaushik, J Singh, R Agarwal, P Rathi, E Kumari - researchgate.net
Although proposed in many cases, the ternary complexation during periodate oxidation of
majority of anilines catalyzed by metals like MnII, has not been thoroughly subjected to …

[PDF][PDF] NEW METHOD FOR MICROGRAM DETERMINATION OF p-PHENETIDINE

RD Kaushik, J Singh, R Saini, P Tyagi… - Rasayan Journal of …, 2017 - rasayanjournal.co.in
The reaction, MnII catalysed reduction of periodate by p-phenetidine in acetone-water
medium is already reported by us to be first order in reactants and catalyst with main …

[PDF][PDF] Research Journal of Pharmaceutical, Biological and Chemical Sciences

HO Hashim, AH Al-Saadi, AH Haider, HK Zaidan - academia.edu
Hypertension is the persisted elevation of blood pressure above the normal rates. About
40% of adults in glob suffered from hypertension which Estimated to cause about 12.8% of …