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Competitive coordination: ambident ligands in the modern chemistry of metal complexes
AD Garnovskii, DA Garnovskii… - Russian chemical …, 1997 - iopscience.iop.org
Data on the problem of competitive coordination, obtained mainly during the last 10 years,
are surveyed and treated systematically. The competitive binding of metals in complexes of …
are surveyed and treated systematically. The competitive binding of metals in complexes of …
cis-[Ru(2,2':6',2' '-terpyridine)(DMSO)Cl2]: Useful Precursor for the Synthesis of Heteroleptic Terpyridine Complexes under Mild Conditions
R Ziessel, V Grosshenny, M Hissler, C Stroh - Inorganic chemistry, 2004 - ACS Publications
[RuII (terpy)(DMSO) Cl2] complexes were synthesized as a 5/1 mixture of cis and trans
isomers, and their reactivities with CO and with substituted 2, 2 ': 6 ', 2 ''-terpyridine (terpy) …
isomers, and their reactivities with CO and with substituted 2, 2 ': 6 ', 2 ''-terpyridine (terpy) …
Catalytic effect of ethylene thiourea on the leaching of chalcopyrite
Chalcopyrite leaching in acidic ferric sulfate media was improved by addition of ethylene
thiourea (ETU) in shaking flask tests with the iron-oxidizing bacterium acidithiobacillus …
thiourea (ETU) in shaking flask tests with the iron-oxidizing bacterium acidithiobacillus …
Ruthenium(II) Bipyridine Complexes: Synthesis and Characterization of Ru(bpy)(CO)2(SCN)2, Ru(dmbpy)(CO)2Cl2, and Ru(dmbpy)(CO)2(NCS)H (bpy = 2,2' …
P Homanen, M Haukka, TA Pakkanen… - …, 1996 - ACS Publications
Ru (II) bipyridine complexes were synthesized and their spectroscopic properties studied.
The replacement of 2, 2 '-bipyridine (bpy) by 6, 6 '-dimethyl-substituted 2, 2 '-bipyridine …
The replacement of 2, 2 '-bipyridine (bpy) by 6, 6 '-dimethyl-substituted 2, 2 '-bipyridine …
Structural evidence of [Rh (Thio) 6] 3+ and [Rh (Thio) 5Cl] 2+ cations in three novel ionic systems based on Co (III) dioximates
PN Bourosh, EB Coropceanu, AP Rija… - Journal of molecular …, 2011 - Elsevier
Multicomponent mixed metal ionic-type dioximates,[Со (DH) 2 (Thio) 2][Rh (Thio) 6][BF 4] 4
(1),[Со (DH) 2 (Thio) 2][Rh (Thio) 6][TiF 6] 2· H 2 O (2) and [Со (NioxH) 2 (Thio) 2] 2 [Rh …
(1),[Со (DH) 2 (Thio) 2][Rh (Thio) 6][TiF 6] 2· H 2 O (2) and [Со (NioxH) 2 (Thio) 2] 2 [Rh …
Activation of thiourea bound through sulfur to pentaammineruthenium (III): structure and reactivity
An X-ray structure of (thiourea) pentaammineruthenium shows an sp3 sulfur atom bonded to
Ru (III). Bond lengths and angles reveal substantial electronic reorganization in the thiourea …
Ru (III). Bond lengths and angles reveal substantial electronic reorganization in the thiourea …
Synthesis and properties of ligand-bridged dinuclear complexes containing trans-bis [o-phenylenebis (dimethylarsine)] chlororuthenium (II) centres
BJ Coe, RL Beddoes, JC Jeffery, SR Batten… - Journal of the …, 1997 - pubs.rsc.org
The series of mononuclear salts trans-[RuCl (pdma) 2 (L–L)] PF 6 [pdma= o-phenylenebis
(dimethylarsine); L–L= 4, 4′-bipyridine (4, 4′-bipy) 2, fumaronitrile (fmn) 4, di-4-pyridyl …
(dimethylarsine); L–L= 4, 4′-bipyridine (4, 4′-bipy) 2, fumaronitrile (fmn) 4, di-4-pyridyl …
Tetramethylthioharnstoff als Ligand in Übergangsmetallkomplexen: Redoxsubstitutionen mit dem Dithiobis(1,1,3,3-tetramethylformamidinium)-Kation Synthese und Kristallstrukturen von [Fe(SR)L3]+BPh4-, [FeL4]2+BPh4-)2 und [RuCl2(CO)2L2] (R = 2,4,6-i-Pr3C6H2; L = SC(NMe2)2) / Tetramethylthiourea as Ligand in Transition Metal Complexes …
U Bierbach, W Barklage, W Saak… - … für Naturforschung B, 1992 - degruyter.com
The oxidation of tetramethylthiourea (SC (NMe2) 2, L) with HC1/H2O2 yields dithiobis-(1, 1,
3, 3-tetramethylformamidinium) dichloride,[{SC (NMe2) 2} 2] 2+ Cl2 (1). Anions in 1 can be …
3, 3-tetramethylformamidinium) dichloride,[{SC (NMe2) 2} 2] 2+ Cl2 (1). Anions in 1 can be …
Synthesis of mer-[RuCl3 (DMSO)(bpy)], reactivity and electrochemistry of mer-[RuCl3 (DMSO)(bpy)] and mer-[RuCl3 (TMSO)(bpy)] complexes
RS Srivastava, FR Fronczek, NR Tarver, RS Perkins - Polyhedron, 2007 - Elsevier
[H (DMSO) 2][trans-RuCl4 (DMSO) 2](1) reacts with 2, 2′-bipyridine in ethanol at room
temperature resulting in the formation of a major compound, mer-[RuCl3 (DMSO)(bpy)](bpy …
temperature resulting in the formation of a major compound, mer-[RuCl3 (DMSO)(bpy)](bpy …
Tuning the reactivity of ruthenium (II) terpyridyl complexes using auxiliary ligands: kinetic and mechanistic studies
Substitution behavior of the labile aqua ligand in four mononuclear ruthenium (II) terpyridyl
complexes with different auxiliary N (pyridine)(Ru1), N^ N (2, 2′-bipyridyl (Ru2), 2′-(2 …
complexes with different auxiliary N (pyridine)(Ru1), N^ N (2, 2′-bipyridyl (Ru2), 2′-(2 …