Directed self-assembly of block copolymers: a tutorial review of strategies for enabling nanotechnology with soft matter

H Hu, M Gopinadhan, CO Osuji - Soft matter, 2014 - pubs.rsc.org
Self-assembly of soft materials is broadly considered an attractive means of generating
nanoscale structures and patterns over large areas. However, the spontaneous formation of …

Designing high χ copolymer materials for nanotechnology applications: A systematic bulk vs. thin films approach

PP Angelopoulou, I Moutsios, GM Manesi… - Progress in Polymer …, 2022 - Elsevier
This review article discusses the origins of self-assembly behavior of linear and non-linear
block co-and terpolymers and their application towards the fabrication of high-resolution …

Solvent vapor annealing of block polymer thin films

C Sinturel, M Vayer, M Morris, MA Hillmyer - Macromolecules, 2013 - ACS Publications
This Perspective provides a critical analysis of the current knowledge concerning solvent
vapor annealing (SVA) of block polymer thin films. Herein, we identify key challenges that …

Chemical patterns for directed self-assembly of lamellae-forming block copolymers with density multiplication of features

CC Liu, A Ramírez-Hernández, E Han… - …, 2013 - ACS Publications
Lamellae-forming polystyrene-block-poly (methyl methacrylate)(PS-b-PMMA) films, with bulk
period L 0, were directed to assemble on lithographically nanopatterned surfaces. The …

Fabrication of nanoporous alumina ultrafiltration membrane with tunable pore size using block copolymer templates

C Zhou, T Segal‐Peretz, ME Oruc… - Advanced Functional …, 2017 - Wiley Online Library
Control over nanopore size and 3D structure is necessary to advance membrane
performance in ubiquitous separation devices. Here, inorganic nanoporous membranes are …

Perpendicular orientation control without interfacial treatment of RAFT-synthesized high-χ block copolymer thin films with sub-10 nm features prepared via thermal …

R Nakatani, H Takano, A Chandra… - … Applied Materials & …, 2017 - ACS Publications
In this study, a series of perpendicular lamellae-forming poly (polyhedral oligomeric
silsesquioxane methacrylate-block-2, 2, 2-trifluoroethyl methacrylate) s (PMAPOSS-b …

Domain Orientation and Grain Coarsening in Cylinder-Forming Poly(styrene-b-methyl methacrylate) Films

S Ji, CC Liu, W Liao, AL Fenske, GSW Craig… - …, 2011 - ACS Publications
The domain orientation and grain sizes in cylinder-forming poly (styrene-b-methyl
methacrylate)(PS-b-PMMA) films were systematically investigated as a function of film …

Polymeric cross-linked surface treatments for controlling block copolymer orientation in thin films

CM Bates, JR Strahan, LJ Santos, BK Mueller… - Langmuir, 2011 - ACS Publications
The orientation of cylinder-forming poly (styrene-block-methyl methacrylate)[P (Sb-MMA)]
was investigated on two sets of polymeric surface treatments: 10 para-substituted …

Perpendicularly oriented sub-10-nm block copolymer lamellae by atmospheric thermal annealing for one minute

T Seshimo, R Maeda, R Odashima, Y Takenaka… - Scientific reports, 2016 - nature.com
The directed self-assembly (DSA) of block co-polymers (BCPs) can realize next-generation
lithography for semiconductors and a variety of soft materials. It is imperative to …

Block copolymer assembly on nanoscale patterns of polymer brushes formed by electrohydrodynamic jet printing

MS Onses, A Ramírez-Hernández, SM Hur, E Sutanto… - ACS …, 2014 - ACS Publications
Fundamental understanding of the self-assembly of domains in block copolymers (BCPs)
and capabilities in control of these processes are important for their use as nanoscale …