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Directed self-assembly of block copolymers: a tutorial review of strategies for enabling nanotechnology with soft matter
Self-assembly of soft materials is broadly considered an attractive means of generating
nanoscale structures and patterns over large areas. However, the spontaneous formation of …
nanoscale structures and patterns over large areas. However, the spontaneous formation of …
Designing high χ copolymer materials for nanotechnology applications: A systematic bulk vs. thin films approach
This review article discusses the origins of self-assembly behavior of linear and non-linear
block co-and terpolymers and their application towards the fabrication of high-resolution …
block co-and terpolymers and their application towards the fabrication of high-resolution …
Solvent vapor annealing of block polymer thin films
This Perspective provides a critical analysis of the current knowledge concerning solvent
vapor annealing (SVA) of block polymer thin films. Herein, we identify key challenges that …
vapor annealing (SVA) of block polymer thin films. Herein, we identify key challenges that …
Chemical patterns for directed self-assembly of lamellae-forming block copolymers with density multiplication of features
Lamellae-forming polystyrene-block-poly (methyl methacrylate)(PS-b-PMMA) films, with bulk
period L 0, were directed to assemble on lithographically nanopatterned surfaces. The …
period L 0, were directed to assemble on lithographically nanopatterned surfaces. The …
Fabrication of nanoporous alumina ultrafiltration membrane with tunable pore size using block copolymer templates
Control over nanopore size and 3D structure is necessary to advance membrane
performance in ubiquitous separation devices. Here, inorganic nanoporous membranes are …
performance in ubiquitous separation devices. Here, inorganic nanoporous membranes are …
Perpendicular orientation control without interfacial treatment of RAFT-synthesized high-χ block copolymer thin films with sub-10 nm features prepared via thermal …
R Nakatani, H Takano, A Chandra… - … Applied Materials & …, 2017 - ACS Publications
In this study, a series of perpendicular lamellae-forming poly (polyhedral oligomeric
silsesquioxane methacrylate-block-2, 2, 2-trifluoroethyl methacrylate) s (PMAPOSS-b …
silsesquioxane methacrylate-block-2, 2, 2-trifluoroethyl methacrylate) s (PMAPOSS-b …
Domain Orientation and Grain Coarsening in Cylinder-Forming Poly(styrene-b-methyl methacrylate) Films
The domain orientation and grain sizes in cylinder-forming poly (styrene-b-methyl
methacrylate)(PS-b-PMMA) films were systematically investigated as a function of film …
methacrylate)(PS-b-PMMA) films were systematically investigated as a function of film …
Polymeric cross-linked surface treatments for controlling block copolymer orientation in thin films
CM Bates, JR Strahan, LJ Santos, BK Mueller… - Langmuir, 2011 - ACS Publications
The orientation of cylinder-forming poly (styrene-block-methyl methacrylate)[P (Sb-MMA)]
was investigated on two sets of polymeric surface treatments: 10 para-substituted …
was investigated on two sets of polymeric surface treatments: 10 para-substituted …
Perpendicularly oriented sub-10-nm block copolymer lamellae by atmospheric thermal annealing for one minute
T Seshimo, R Maeda, R Odashima, Y Takenaka… - Scientific reports, 2016 - nature.com
The directed self-assembly (DSA) of block co-polymers (BCPs) can realize next-generation
lithography for semiconductors and a variety of soft materials. It is imperative to …
lithography for semiconductors and a variety of soft materials. It is imperative to …
Block copolymer assembly on nanoscale patterns of polymer brushes formed by electrohydrodynamic jet printing
Fundamental understanding of the self-assembly of domains in block copolymers (BCPs)
and capabilities in control of these processes are important for their use as nanoscale …
and capabilities in control of these processes are important for their use as nanoscale …