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% V Bur index and steric maps: from predictive catalysis to machine learning
S Escayola, N Bahri-Laleh, A Poater - Chemical Society Reviews, 2024 - pubs.rsc.org
Steric indices are parameters used in chemistry to describe the spatial arrangement of
atoms or groups of atoms in molecules. They are important in determining the reactivity …
atoms or groups of atoms in molecules. They are important in determining the reactivity …
The golden age of transfer hydrogenation
D Wang, D Astruc - Chemical reviews, 2015 - ACS Publications
Hydrogenation is one of the most fundamental transformations in organic synthesis, and its
industrial applications span from fine chemicals to pharmaceuticals synthesis. 1− 3 Direct …
industrial applications span from fine chemicals to pharmaceuticals synthesis. 1− 3 Direct …
Advances in the Synthesis and Applications of N-Heterocyclic Carbene Metal Complexes with a Focus on the Weak Base Route
T Scattolin, AA Logvinov, NV Tzouras, CSJ Cazin… - …, 2023 - ACS Publications
N-heterocyclic carbene (NHC) ligands have evolved from being simple lab curiosities to
tertiary phosphine mimics to finally take center stage as unique supporting ligands in …
tertiary phosphine mimics to finally take center stage as unique supporting ligands in …
N-heterocyclic carbenes in late transition metal catalysis
S Diez-Gonzalez, N Marion, SP Nolan - Chemical Reviews, 2009 - ACS Publications
N-Heterocyclic carbenes (NHCs) are cyclic carbenes bearing at least one R-amino
substituent. 1 The most common subclasses of NHCs are represented in Chart 1. Early work …
substituent. 1 The most common subclasses of NHCs are represented in Chart 1. Early work …
Percent buried volume for phosphine and N-heterocyclic carbene ligands: steric properties in organometallic chemistry
H Clavier, SP Nolan - Chemical communications, 2010 - pubs.rsc.org
Electronic and steric ligand effects both play major roles in organometallic chemistry and
consequently in metal-mediated catalysis. Quantifying such parameters is of interest to …
consequently in metal-mediated catalysis. Quantifying such parameters is of interest to …
N‐heterocyclic carbenes: a new concept in organometallic catalysis
WA Herrmann - Angewandte Chemie International Edition, 2002 - Wiley Online Library
N‐Heterocyclic carbenes have become universal ligands in organometallic and inorganic
coordination chemistry. They not only bind to any transition metal, be it in low or high …
coordination chemistry. They not only bind to any transition metal, be it in low or high …
SambVca: A Web Application for the Calculation of the Buried Volume of N‐Heterocyclic Carbene Ligands
We present a free web application for the calculation of the buried volume (% VBur) of NHC
ligands. The web application provides a graphic and user‐friendly interface to the SambVca …
ligands. The web application provides a graphic and user‐friendly interface to the SambVca …
Understanding the M (NHC)(NHC= N-heterocyclic carbene) bond
H Jacobsen, A Correa, A Poater, C Costabile… - Coordination Chemistry …, 2009 - Elsevier
N-heterocyclic carbenes (NHC) is a well established class of new ligands in organometallic
chemistry. Their use as ligands in many reactions catalyzed by transition metal complexes …
chemistry. Their use as ligands in many reactions catalyzed by transition metal complexes …
N-heterocyclic carbene transition metal complexes for catalysis in aqueous media
HD Velazquez, F Verpoort - Chemical Society Reviews, 2012 - pubs.rsc.org
The last decade has seen an increasing number of reports on the use of NHC–metal
complexes for catalysis in water, therefore this review is aimed to introduce the whole …
complexes for catalysis in water, therefore this review is aimed to introduce the whole …
Steric and Electronic Properties of N-Heterocyclic Carbenes (NHC): A Detailed Study on Their Interaction with Ni(CO)4
R Dorta, ED Stevens, NM Scott… - Journal of the …, 2005 - ACS Publications
N-heterocyclic carbene ligands IMes (1), SIMes (2), IPr (3), SIPr (4), and ICy (5) react with Ni
(CO) 4 to give the saturated tricarbonyl complexes Ni (CO) 3 (IMes)(8), Ni (CO) 3 (SIMes)(9) …
(CO) 4 to give the saturated tricarbonyl complexes Ni (CO) 3 (IMes)(8), Ni (CO) 3 (SIMes)(9) …