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Chemo-and stereoselective CH oxidations and epoxidations/cis-dihydroxylations with H2O2, catalyzed by non-heme iron and manganese complexes
EP Talsi, KP Bryliakov - Coordination Chemistry Reviews, 2012 - Elsevier
The discovery of simple and efficient catalyst systems for the selective oxofunctionalization
of hydrocarbons is a challenging task of modern chemistry. The biomimetic approach, which …
of hydrocarbons is a challenging task of modern chemistry. The biomimetic approach, which …
[HTML][HTML] Oxidation of organic compounds with peroxides catalyzed by polynuclear metal compounds
GB Shul'pin, LS Shul'pina - Catalysts, 2021 - mdpi.com
The review describes articles that provide data on the synthesis and study of the properties
of catalysts for the oxidation of alkanes, olefins, and alcohols. These catalysts are …
of catalysts for the oxidation of alkanes, olefins, and alcohols. These catalysts are …
Anchoring a Molecular Iron Catalyst to Solar-Responsive WO3 Improves the Rate and Selectivity of Photoelectrochemical Water Oxidation
BM Klepser, BM Bartlett - Journal of the American Chemical …, 2014 - ACS Publications
Molecular catalysts help overcome the kinetic limitations of water oxidation and generally
result in faster rates for water oxidation than do heterogeneous catalysts. However …
result in faster rates for water oxidation than do heterogeneous catalysts. However …
A colorimetric sensor for the highly selective, ultra-sensitive, and rapid detection of volatile organic compounds and hazardous gases
L Sun, A Rotaru, K Robeyns… - Industrial & Engineering …, 2021 - ACS Publications
We present a new colorimetric chemosensor of formula [Fe (H2btm) 2 (H2O) 2] Cl2
(1)(H2btm= di (1 H-tetrazol-5-yl) methane), allowing to detect at real time, with a high …
(1)(H2btm= di (1 H-tetrazol-5-yl) methane), allowing to detect at real time, with a high …
Detecting Fe (II) Spin-Crossover by Modulation of Appended Eu (III) Luminescence in a Single Molecule
N Deorukhkar, C Egger, L Guénée… - Journal of the …, 2023 - ACS Publications
Multifunctionality in spin-crossover (SCO) devices is limited to macroscopic or nanoscopic
materials because of the need for long-range effects for inducing favorable cooperativity …
materials because of the need for long-range effects for inducing favorable cooperativity …
Oxidation of cyclohexane by transition-metal complexes with biomimetic ligands
AR Silva, T Mourão, J Rocha - Catalysis Today, 2013 - Elsevier
This work reports the catalytic activity, in homogeneous phase, of transition-metal complexes
of the first-row (V (IV), Mn (III), Fe (III) Co (III) and Cu (II)) with biomimetic Schiff base ligands …
of the first-row (V (IV), Mn (III), Fe (III) Co (III) and Cu (II)) with biomimetic Schiff base ligands …
Assessing the Impact of Electronic and Steric Tuning of the Ligand in the Spin State and Catalytic Oxidation Ability of the FeII(Pytacn) Family of Complexes
I Prat, A Company, T Corona, T Parella… - Inorganic …, 2013 - ACS Publications
A family of iron complexes with the general formula [FeII (R, R′ Pytacn)(X) 2] n+ is
described, where R, R′ Pytacn is the tetradentate ligand 1-[(4-R′-6-R-2-pyridyl) methyl]-4 …
described, where R, R′ Pytacn is the tetradentate ligand 1-[(4-R′-6-R-2-pyridyl) methyl]-4 …
New iron (II) α-iminopyridine complexes and their catalytic activity in the oxidation of activated methylene groups and secondary alcohols to ketones
A set of iron (II) complexes of the general formula [Fe (OTf) 2L2] was synthesized in 32 to
78% isolated yields, where L represents a bidentate α-iminopyridine ligand. Four of the iron …
78% isolated yields, where L represents a bidentate α-iminopyridine ligand. Four of the iron …
Spin crossover, reversible redox, and supramolecular interactions in 3d complexes of 4-(4-pyridyl)-2, 5-dipyrazyl-pyridine
RG Miller, S Brooker - Inorganic chemistry, 2015 - ACS Publications
A new terpyridine-inspired terdentate ligand, 4-(4-pyridyl)-2, 5-dipyrazyl-pyridine (py-
pzpypz), featuring three “spare” nitrogen donors “out the back”, has been used to synthesize …
pzpypz), featuring three “spare” nitrogen donors “out the back”, has been used to synthesize …
Combining NMR of dynamic and paramagnetic molecules: fluxional high-spin nickel (II) complexes bearing bisguanidine ligands
P Roquette, A Maronna, M Reinmuth, E Kaifer… - Inorganic …, 2011 - ACS Publications
A detailed nuclear magnetic resonance (NMR) study was carried out on a series of
paramagnetic, tetrahedrally coordinated nickel (II) dihalide complexes featuring chelating …
paramagnetic, tetrahedrally coordinated nickel (II) dihalide complexes featuring chelating …