Mesoionic carbenes (MICs) of the 1, 2, 3-triazolylidene type have established themselves as
a popular class of compounds over the past decade. Primary reasons for this popularity are …

Triazole-derived N-heterocyclic carbenes, triazolylidenes (trz) have become an interesting
alternative to the ubiquitous Arduengo-type imidazole-derived carbenes, in part because …

We report the synthesis of vanadium (V) oxo complex 1 with a pincer-type dianionic
mesoionic carbene (MIC) ligand L 1 and the general formula [VOCl (L1)]. A comparison of …

We report the synthesis and the reactivity of 1, 2, 3‐triazolin‐5‐imine type mesoionic imines
(MIIs). The MIIs are accessible by a base‐mediated cycloaddition between a substituted …

N‐heterocyclic imines are widely used in transition‐metal chemistry, main‐group chemistry
as well as catalysis, due to their enhanced basicity and nucleophilicity which benefit from …

This chapter discusses recent developments on the conversion of CO2 into compounds
such as formates and methanol, in addition to looking at utilising CO2 for N-methylation …

Mesoionic carbenes (MIC) of the 1, 2, 3‐triazol‐5‐ylidene type are currently popular ligands
in organometallic chemistry. Their use in main group chemistry has been rather limited. In …

Control of the spin state of metal complexes is important because it leads to a precise control
over the physical properties and the chemical reactivity of the metal complexes. Currently …

Wir berichten über die Synthese und die Reaktivität mesoionischer Imine (MIIs) des 1, 2, 3‐
Triazolin‐5‐imin Typs. Die MIIs sind über eine Basen‐mediierte Cycloaddition eines …

Triazolylidene ligands belong to a class of N-heterocyclic carbenes of growing chemical
interest. Their precursors are readily available using Click chemistry and, therefore, highly …