An initial review (PCET1) on proton-coupled electron transfer (PCET) by Huynh and Meyer
appeared in Chemical Reviews in 2007.(1) This is a follow-up on the original. It was …

This paper reviews several p K a calculation strategies that are commonly used in aqueous
acidity predictions. Among those investigated were the direct or absolute method, the proton …

Alternative approaches for producing ammonia are necessary to reduce the environmental
impact of its production. The lithium-mediated electrochemical nitrogen reduction reaction …

The second edition of Pharmaceutical Stress Testing: Predicting Drug Degradation provides
a practical and scientific guide to designing, executing, and interpreting stress testing …

The equilibrium acidity scale (pKa scale) in acetonitrile has been supplemented by
numerous new compounds and new ΔpKa measurements. It now contains altogether 231 …

The p K a's of substituted thiols are important for understanding their properties and
reactivities in applications in chemistry, biochemistry, and material chemistry. For a …

A general method for the light-driven intermolecular anti-Markovnikov hydroamination of
alkenes with primary sulfonamides, sulfamides, and sulfamates is presented. The reaction is …

Continuum solvent calculations of pKas and reduction potentials usually entail the use of a
thermodynamic cycle to express the reaction free energy in terms of gas phase energies and …

Hybrid discrete‐continuum approaches for solvation have been widely applied for diverse
problems in chemistry suck as pKa calculation in aqueous and nonaqueous solvents …

An empirical conversion method (ECM) that transforms p K a values of arbitrary organic
compounds from one solvent to the other is introduced. We demonstrate the method's …