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The comparison between single atom catalysis and surface organometallic catalysis
Single atom catalysis (SAC) is a recent discipline of heterogeneous catalysis for which a
single atom on a surface is able to carry out various catalytic reactions. A kind of revolution …
single atom on a surface is able to carry out various catalytic reactions. A kind of revolution …
Direct and cost-efficient hyperpolarization of long-lived nuclear spin states on universal 15N2-diazirine molecular tags
Conventional magnetic resonance (MR) faces serious sensitivity limitations which can be
overcome by hyperpolarization methods, but the most common method (dynamic nuclear …
overcome by hyperpolarization methods, but the most common method (dynamic nuclear …
Rational design of dinitroxide biradicals for efficient cross-effect dynamic nuclear polarization
DJ Kubicki, G Casano, M Schwarzwälder, S Abel… - Chemical …, 2016 - pubs.rsc.org
A series of 37 dinitroxide biradicals have been prepared and their performance studied as
polarizing agents in cross-effect DNP NMR experiments at 9.4 T and 100 K in 1, 1, 2, 2 …
polarizing agents in cross-effect DNP NMR experiments at 9.4 T and 100 K in 1, 1, 2, 2 …
Dynamic nuclear polarization opens new perspectives for NMR spectroscopy in analytical chemistry
B Plainchont, P Berruyer, JN Dumez, S Jannin… - 2018 - ACS Publications
Dynamic nuclear polarization (DNP) can boost sensitivity in nuclear magnetic resonance
(NMR) experiments by several orders of magnitude. This Feature illustrates how the …
(NMR) experiments by several orders of magnitude. This Feature illustrates how the …
High-resolution NMR spectroscopy of encapsulated proteins dissolved in low-viscosity fluids
High-resolution multi-dimensional solution NMR is unique as a biophysical and biochemical
tool in its ability to examine both the structure and dynamics of macromolecules at atomic …
tool in its ability to examine both the structure and dynamics of macromolecules at atomic …
Room-temperature dynamic nuclear polarization enhanced NMR spectroscopy of small biological molecules in water
Nuclear magnetic resonance (NMR) spectroscopy is a powerful and popular technique for
probing the molecular structures, dynamics and chemical properties. However the …
probing the molecular structures, dynamics and chemical properties. However the …
Tailoring of Polarizing Agents in the bTurea Series for Cross‐Effect Dynamic Nuclear Polarization in Aqueous Media
C Sauvée, G Casano, S Abel… - … A European Journal, 2016 - Wiley Online Library
A series of 18 nitroxide biradicals derived from bTurea has been prepared, and their
enhancement factors ɛ (1H) in cross‐effect dynamic nuclear polarization (CE DNP) NMR …
enhancement factors ɛ (1H) in cross‐effect dynamic nuclear polarization (CE DNP) NMR …
Frozen acrylamide gels as dynamic nuclear polarization matrices
Aqueous acrylamide gels can be used to provide dynamic nuclear polarization (DNP) NMR
signal enhancements of around 200 at 9.4 T and 100 K. The enhancements are shown to …
signal enhancements of around 200 at 9.4 T and 100 K. The enhancements are shown to …
Tailored polarizing hybrid solids with nitroxide radicals localized in mesostructured silica walls
DL Silverio, HA Van Kalkeren, TC Ong… - Helvetica Chimica …, 2017 - Wiley Online Library
Hyperpolarization by dynamic nuclear polarization relies on the microwave irradiation of
paramagnetic radicals dispersed in molecular glasses to enhance the nuclear magnetic …
paramagnetic radicals dispersed in molecular glasses to enhance the nuclear magnetic …
Optically generated hyperpolarization for sensitivity enhancement in solution-state NMR spectroscopy
MW Dale, CJ Wedge - Chemical Communications, 2016 - pubs.rsc.org
We show that optical excitation of radical triplet pair systems can produce a fourfold NMR
signal enhancement in solution, without the need for microwave pum**. Development of …
signal enhancement in solution, without the need for microwave pum**. Development of …