Palladium/norbornene cooperative catalysis

J Wang, G Dong - Chemical reviews, 2019 - ACS Publications
Palladium/norbornene cooperative catalysis has emerged as a distinct approach to
construct polyfunctionalized arenes from readily available starting materials. This Review …

Metal–organic cooperative catalysis in C–H and C–C bond activation

DS Kim, WJ Park, CH Jun - Chemical Reviews, 2017 - ACS Publications
Transition-metal-catalyzed activation of C–H and C–C bonds is a challenging area in
synthetic organic chemistry. Among various methods to accomplish these processes, the …

Recent progress on Catellani reaction

Z Chen, F Zhang - Tetrahedron, 2023 - Elsevier
The Catellani reaction is a palladium-catalyzed hydrocarbon-activated multicomponent
tandem reaction involving an aryl halide, an electrophilic coupling reagent and a terminating …

Cleavage of the C (O)–S bond of thioesters by palladium/norbornene/copper cooperative catalysis: an efficient synthesis of 2-(arylthio) aryl ketones

F Sun, M Li, C He, B Wang, B Li, X Sui… - Journal of the American …, 2016 - ACS Publications
A Pd/norbornene/Cu cooperative catalysis for the efficient synthesis of 2-(arylthio) aryl
ketones from aryl halides and thioesters has been developed. The first example of …

Complementary site-selectivity in arene functionalization enabled by overcoming the ortho constraint in palladium/norbornene catalysis

J Wang, R Li, Z Dong, P Liu, G Dong - Nature Chemistry, 2018 - nature.com
Achieving site-selectivity in arene functionalization that is complementary to the site-
selectivity from electrophilic aromatic substitution reactions has been a long-standing quest …

Site‐Selective Ortho/Ipso C−H Difunctionalizations of Arenes using Thianthrene as a Leaving Group

D Dupommier, M Vuagnat, J Rzayev, S Roy… - Angewandte …, 2024 - Wiley Online Library
Site‐selective ortho/ipso C− H difunctionalizations of aromatic compounds were designed to
afford polyfunctionalized arenes including challenging 1, 2, 3, 4‐tetrasubstituted ones (62 …

Direct annulation between aryl iodides and epoxides through palladium/norbornene cooperative catalysis

R Li, G Dong - Angewandte Chemie International Edition, 2018 - Wiley Online Library
Herein we report a direct annulation between aryl iodides and epoxides through
palladium/norbornene (Pd/NBE) cooperative catalysis. An iso‐propyl ester substituted NBE …

Enantioselective synthesis of biaryl atropisomers via Pd/norbornene-catalyzed three-component cross-couplings

L Ding, X Sui, Z Gu - ACS Catalysis, 2018 - ACS Publications
Three-component cross-coupling cocatalyzed by palladium and norbornene is reported for
the synthesis of biaryl atropisomers. This domino reaction gave optimal yield and …

Modular ipso/ortho Difunctionalization of Aryl Bromides via Palladium/Norbornene Cooperative Catalysis

Z Dong, G Lu, J Wang, P Liu… - Journal of the American …, 2018 - ACS Publications
Palladium/norbornene (Pd/NBE) cooperative catalysis has emerged as a useful tool for
preparing poly substituted arenes; however, its substrate scope has been largely restricted …

Functionalized Cycloolefin Ligand as a Solution to Ortho-Constraint in the Catellani-Type Reaction

FY Wang, YX Li, L Jiao - Journal of the American Chemical …, 2023 - ACS Publications
The Catellani reaction, ie, the Pd/norbornene (NBE) catalysis, has been evolved into a
versatile approach to multisubstituted arenes via the ortho-functionalization/ipso-termination …