Electrochemical and spectroscopic methods for evaluating molecular electrocatalysts
KJ Lee, N Elgrishi, B Kandemir… - Nature Reviews Chemistry, 2017 - nature.com
Modern energy challenges have amplified interest in transition metal-based molecular
electrocatalysts for fuel-forming reactions. The activity of these homogeneous …
electrocatalysts for fuel-forming reactions. The activity of these homogeneous …
Recent developments in hydrogen evolving molecular cobalt (II)–polypyridyl catalysts
The search for efficient noble metal-free hydrogen-evolving catalysts is the subject of intense
research activity. A new family of molecular cobalt (II)–polypyridyl catalysts has recently …
research activity. A new family of molecular cobalt (II)–polypyridyl catalysts has recently …
Turning it off! Disfavouring hydrogen evolution to enhance selectivity for CO production during homogeneous CO 2 reduction by cobalt–terpyridine complexes
Understanding the activity and selectivity of molecular catalysts for CO2 reduction to fuels is
an important scientific endeavour in addressing the growing global energy demand. Cobalt …
an important scientific endeavour in addressing the growing global energy demand. Cobalt …
First-row transition metal polypyridine complexes that catalyze proton to hydrogen reduction
Proton reduction is a critical reaction for the efficient utilization of solar fuels and the
development of a hydrogen economy. Molecular proton reduction catalysts help us to …
development of a hydrogen economy. Molecular proton reduction catalysts help us to …
Reaction pathways of hydrogen-evolving electrocatalysts: electrochemical and spectroscopic studies of proton-coupled electron transfer processes
Proton-coupled electron transfer (PCET) reactions are at the heart of the catalytic processes
involved in hydrogen evolution. In this Perspective, the state-of-the-art spectroscopic and …
involved in hydrogen evolution. In this Perspective, the state-of-the-art spectroscopic and …
Determining the overpotential of electrochemical fuel synthesis mediated by molecular catalysts: Recommended practices, standard reduction potentials, and …
BM Stratakes, JL Dempsey, AJM Miller - ChemElectroChem, 2021 - Wiley Online Library
Molecular catalysts capable of performing electrochemical transformations are frequently
utilized in the synthesis of fuels. A common benchmark for evaluating catalysts for …
utilized in the synthesis of fuels. A common benchmark for evaluating catalysts for …
Tuning the reactivity of cobalt-based H2 production electrocatalysts via the incorporation of the peripheral basic functionalities
The construction of an efficient, inexpensive, and durable H 2 production electrocatalyst is
considered as an indispensable tool for the inception of a hydrogen-mediated alternative …
considered as an indispensable tool for the inception of a hydrogen-mediated alternative …
Three mononuclear octahedral cobalt (III) complexes with salicylaldimine Schiff bases: Synthesis, characterization, phenoxazinone synthase mimicking activity and …
Three mononuclear facial cobalt (III) complexes,[Co (L) 2] ClO 4 (1),[Co (L)(bzan)(N 3)](2)
and [Co (L)(bzan)(NCS)](3),{HL= 2-(3-(dimethylamino) propyliminomethyl)-6-ethoxyphenol …
and [Co (L)(bzan)(NCS)](3),{HL= 2-(3-(dimethylamino) propyliminomethyl)-6-ethoxyphenol …
Ligand-Mediated Hydrogen Evolution by Co (II) Complexes and Assessment of the Mechanism by Computational Studies
In this work, two novel dinuclear cobalt complexes,[CoII (hbqc)(H2O)] 2 (Co-Cl) and [CoII
(hbqn)(H2O)] 2 (Co-NO2), featuring benzimidazole derived redox-active ligand have been …
(hbqn)(H2O)] 2 (Co-NO2), featuring benzimidazole derived redox-active ligand have been …
A smorgasbord of 17 cobalt complexes active for photocatalytic hydrogen evolution
Seventeen cobalt complexes—eleven dinuclear cobalt (II) complexes and three tetranuclear
cobalt complexes (two mixed valent) of ditopic ligands, with varying N‐donor aromatic …
cobalt complexes (two mixed valent) of ditopic ligands, with varying N‐donor aromatic …