Unifying nonlinear response and incoherent mixing in action-2D electronic spectroscopy

M Bruschi, L Bolzonello, F Gallina… - The Journal of Physical …, 2023 - ACS Publications
Action-detection has expanded the scope and applicability of 2D electronic spectroscopy,
while posing new challenges for the unambiguous interpretation of spectral features. In this …

Nonlinear optical spectroscopy of molecular assemblies: What is gained and lost in action detection?

L Bolzonello, M Bruschi, B Fresch… - The Journal of Physical …, 2023 - ACS Publications
This study elucidates the information content that is extracted from action-2D electronic
spectroscopy (A-2DES) when the output intensity is not proportional to the number of …

Expanding the bandwidth of fluorescence-detected two-dimensional electronic spectroscopy using a broadband continuum probe pulse pair

SE Sanders, M Zhang, A Javed, JP Ogilvie - Optics Express, 2024 - opg.optica.org
We demonstrate fluorescence-detected two-dimensional electronic spectroscopy (F-2DES)
with a broadband, continuum probe pulse pair in the pump-probe geometry. The approach …

Photosynthetic energy transfer: Missing in action (detected spectroscopy)?

A Javed, J Lüttig, K Charvátová… - The Journal of …, 2024 - ACS Publications
In recent years, action-detected ultrafast spectroscopies have gained popularity offering
distinct advantages over their coherently detected counterparts, such as spatially resolved …

Photoelectrochemical Two-Dimensional Electronic Spectroscopy (PEC2DES) of Photosystem I: Charge Separation Dynamics Hidden in a Multichromophoric …

M López-Ortiz, L Bolzonello, M Bruschi… - … Applied Materials & …, 2024 - ACS Publications
We present a nonlinear spectroelectrochemical technique to investigate photosynthetic
protein complexes. The PEC2DES setup combines photoelectrochemical detection (PEC) …

A spectrometer design that eliminates incoherent mixing signals in 2D action spectroscopies

ZM Faitz, D Im, CJ Blackwell, MS Arnold… - The Journal of Chemical …, 2024 - pubs.aip.org
Action spectroscopies use a readout created by the action of light on the molecules or
material rather than optical absorption. Ultrafast 2D photocurrent and 2D fluorescence …

Uncovering transport mechanisms in perovskite materials and devices with recombination-induced action spectroscopies

MG McNamee, Z Ouyang, L Yan, Z Gan… - The Journal of …, 2023 - ACS Publications
Although valuable insights are derived from conventional spectroscopic approaches, the
understanding of a photovoltaic device's operation mechanisms can be limited in ex situ …

Resolving nonlinear recombination dynamics in semiconductors via ultrafast excitation correlation spectroscopy: Photoluminescence versus photocurrent detection

E Rojas-Gatjens, KM Yallum, Y Shi… - The Journal of …, 2023 - ACS Publications
We explore the application of excitation correlation spectroscopy to detect nonlinear
photophysical dynamics in two distinct semiconductor classes through time-integrated …

Two-Dimensional Spectroscopy of Open Quantum Systems: Nonequilibrium Green's Function Formulation

H Sun, U Harbola, S Mukamel… - The Journal of Physical …, 2025 - ACS Publications
Two-dimensional spectroscopy is examined for open quantum systems featuring multiple
simultaneously measurable fluxes. Specifically, we explore a junction where optical …

[HTML][HTML] Exciton–photocarrier interference in mixed lead-halide-perovskite nanocrystals

E Rojas-Gatjens, QA Akkerman, L Manna… - The Journal of …, 2024 - pubs.aip.org
The use of semiconductor nanocrystals in scalable quantum technologies requires
characterization of the exciton coherence dynamics in an ensemble of electronically isolated …