Molecular magnetism, quo vadis? A historical perspective from a coordination chemist viewpoint☆

J Ferrando-Soria, J Vallejo, M Castellano… - Coordination Chemistry …, 2017 - Elsevier
Molecular magnetism has travelled a long way from the pioneering studies on electron
exchange and double exchange or spin crossover and valence tautomerism in small …

Low-coordinate mononuclear lanthanide complexes as molecular nanomagnets

AK Bar, P Kalita, MK Singh, G Rajaraman… - Coordination Chemistry …, 2018 - Elsevier
The discovery that some bis-(phthalocyaninato) lanthanide complexes are molecular
magnets triggered interest in lanthanide ion complexes. Theoretical and experimental …

A Complete Ab Initio View of Orbach and Raman Spin–Lattice Relaxation in a Dysprosium Coordination Compound

M Briganti, F Santanni, L Tesi, F Totti… - Journal of the …, 2021 - ACS Publications
The unique electronic and magnetic properties of lanthanide molecular complexes place
them at the forefront of the race toward high-temperature single-molecule magnets and …

Strategies toward high-temperature lanthanide-based single-molecule magnets

L Ungur, LF Chibotaru - Inorganic Chemistry, 2016 - ACS Publications
Lanthanide-based single-molecule magnets are leading materials for achieving
magnetization blocking at the level of one molecule. In this paper, we examine the physical …

Discovery of a dysprosium metallocene single-molecule magnet with two high-temperature Orbach processes

FS Guo, M He, GZ Huang, SR Giblin… - Inorganic …, 2022 - ACS Publications
Magnetic bistability in single-molecule magnets (SMMs) is a potential basis for new types of
nanoscale information storage material. The standard model for thermally activated …

Water-driven reversible switching of single-ion magnetism and proton conduction in a dysprosium sulfonate

D Shao, WJ Tang, Z Ruan, X Yang, L Shi… - Inorganic Chemistry …, 2022 - pubs.rsc.org
We report the design and synthesis of a 1D Dy (III) coordination polymer, comprised of
sulfonate functionalised ligand 8-hydroxyquinoline-5-sulfonic acid (H2SQ) and Dy3+ ions …

Magnetic Anisotropy Trends along a Full 4f-Series: The fn+7 Effect

M Briganti, E Lucaccini, L Chelazzi… - Journal of the …, 2021 - ACS Publications
The combined experimental and computational study of the 13 magnetic complexes
belonging to the Na [LnDOTA (H2O)](H4DOTA= tetraazacyclododecane-N, N′, N ″, N …

A method to predict both the relaxation time of quantum tunneling of magnetization and the effective barrier of magnetic reversal for a Kramers single-ion magnet

B Yin, CC Li - Physical Chemistry Chemical Physics, 2020 - pubs.rsc.org
In this work, a theoretical method for the prediction of both the relaxation time of quantum
tunneling of magnetization (τQTM) and the effective barrier of magnetic reversal (Ueff) is …

A planar triangular Dy 3+ Dy 3 single-molecule magnet with a toroidal magnetic moment

XL Li, J Wu, J Tang, B Le Guennic, W Shi… - Chemical …, 2016 - pubs.rsc.org
A planar triangular Dy 3 + Dy 3 single-molecule magnet with a toroidal magnetic moment -
Chemical Communications (RSC Publishing) DOI:10.1039/C6CC05326B Royal Society of …

Covalency and magnetic anisotropy in lanthanide single molecule magnets: the DyDOTA archetype

M Briganti, GF Garcia, J Jung, R Sessoli… - Chemical …, 2019 - pubs.rsc.org
Lanthanide ions when complexed by polyamino-polycarboxylate chelators form a class of
compounds of paramount importance in several research and technological areas …