Recent Advances in Alkenyl sp2 C–H and C–F Bond Functionalizations: Scope, Mechanism, and Applications

MZ Lu, J Goh, M Maraswami, Z Jia, JS Tian… - Chemical …, 2022 - ACS Publications
Alkenes and their derivatives are featured widely in a variety of natural products,
pharmaceuticals, and advanced materials. Significant efforts have been made toward the …

3d transition metals for C–H activation

P Gandeepan, T Müller, D Zell, G Cera… - Chemical …, 2018 - ACS Publications
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

Weak-coordination in C–H bond functionalizations catalyzed by 3d metals

R Mandal, B Garai, B Sundararaju - ACS Catalysis, 2022 - ACS Publications
Transition-metal-catalyzed C–H bond functionalizations have had an enormous influence on
organic synthesis in recent times. However, the use of low-abundance 4d and 5d metals is …

Carbon trifluoromethylation reactions of hydrocarbon derivatives and heteroarenes

C Alonso, E Martinez de Marigorta, G Rubiales… - Chemical …, 2015 - ACS Publications
Fluorine has emerged as a “magic element” in medicinal chemistry, crop, and materials
science. 1 Although fluorine is the most abundant halogen in the earth's crust, it is contained …

Good partnership between sulfur and fluorine: sulfur-based fluorination and fluoroalkylation reagents for organic synthesis

C Ni, M Hu, J Hu - Chemical Reviews, 2015 - ACS Publications
Fluorine, often called as “a small atom with a big ego”, 1 lies in the second row and the 17th
column in the periodic table of the chemical elements. This unique position in the periodic …

Recent advances in trifluoromethylation reactions with electrophilic trifluoromethylating reagents

S Barata‐Vallejo, B Lantaño… - Chemistry–A European …, 2014 - Wiley Online Library
Electrophilic trifluoromethylation reactions have been the latest approach to achieve the
fluoroalkylation of compounds with newly‐discovered reagents, such as the Togni's (1 …

Recent Progress in Direct Introduction of Fluorinated Groups on Alkenes and Alkynes by means of C H Bond Functionalization

T Besset, T Poisson… - Chemistry–A European …, 2014 - Wiley Online Library
The direct introduction of fluorine and fluorinated building blocks has recently attracted a lot
of attention and particularly the direct functionalization of alkenes and alkynes. This review …

Recent advances in N-heterocyclic carbene (NHC) catalyzed fluorination and fluoroalkylation

Z **, F Zhang, X **ao, N Wang, X Lv… - Organic Chemistry …, 2024 - pubs.rsc.org
Fluorine and fluoroalkyl groups wildly exist in organic molecules that are useful in numerous
fields such as biological chemistry, medicinal science, agrochemistry, materials science and …

Recent advances in trifluoromethylation of organic compounds using Umemoto's reagents

C Zhang - Organic & Biomolecular Chemistry, 2014 - pubs.rsc.org
The incorporation of fluorine-containing moieties into organic compounds is of great
importance in pharmaceutical, agricultural, and materials science. Within these …

Chemo-, regio-, and stereoselective trifluoromethylation of styrenes via visible light-driven single-electron transfer (SET) and triplet–triplet energy transfer (TTET) …

QY Lin, XH Xu, FL Qing - The Journal of Organic Chemistry, 2014 - ACS Publications
A process for tunable and chemo-, regio-, and stereoselective photocatalytic
trifluoromethylation of styrenes was developed. Thermodynamically stable E …