Experimental evidence of long-lived electric fields of ionic liquid bilayers

M Belotti, X Lyu, L Xu, P Halat, N Darwish… - Journal of the …, 2021 - ACS Publications
Herein we demonstrate that ionic liquids can form long-lived double layers, generating
electric fields detectable by straightforward open circuit potential (OCP) measurements. In …

Hysteresis of potential-dependent changes in ion density and structure of an ionic liquid on a gold electrode: in situ observation by surface-enhanced infrared …

K Motobayashi, K Minami, N Nishi… - The Journal of …, 2013 - ACS Publications
Potential-dependent structure and dynamics of 1-butyl-3-methylimidazolium bis (
trifluoromethanesulfonyl) amide ([BMIM][TFSA]) on an Au electrode have been investigated …

Structural origins of potential dependent hysteresis at the electrified graphene/ionic liquid interface

A Uysal, H Zhou, G Feng, SS Lee, S Li… - The Journal of …, 2014 - ACS Publications
We studied the potential and time-dependent changes in the electric double layer (EDL)
structure of an imidazolium-based room temperature ionic liquid (RTIL) electrolyte at an …

In situ PM-IRRAS of a glassy carbon electrode/deep eutectic solvent interface

L Vieira, R Schennach, B Gollas - Physical Chemistry Chemical …, 2015 - pubs.rsc.org
The interface of a 1: 2 molar choline chloride/ethylene glycol deep eutectic solvent with a
glassy carbon electrode has been investigated by polarization modulation reflection …

Interfacial ionic 'liquids': connecting static and dynamic structures

A Uysal, H Zhou, G Feng, SS Lee, S Li… - Journal of Physics …, 2014 - iopscience.iop.org
It is well known that room temperature ionic liquids (RTILs) often adopt a charge-separated
layered structure, ie with alternating cation-and anion-rich layers, at electrified interfaces …

From solvent-free to dilute electrolytes: Essential components for a continuum theory

N Gavish, D Elad, A Yochelis - The journal of physical chemistry …, 2018 - ACS Publications
The increasing number of experimental observations on highly concentrated electrolytes
and ionic liquids show qualitative features that are distinct from dilute or moderately …

Development of local analysis technique of electric double layer at electrode interfaces and its application to ionic liquid interfaces

K Fukui - Bulletin of the Chemical Society of Japan, 2018 - academic.oup.com
Local analyses of electrolyte/solid electrode interfaces at controlled electrode potentials are
of fundamental importance to understanding the origin and properties of the electric double …

Ultraslow relaxation of the structure at the ionic liquid| gold electrode interface to a potential step probed by electrochemical surface plasmon resonance …

N Nishi, Y Hirano, T Motokawa… - Physical Chemistry …, 2013 - pubs.rsc.org
The relaxation of the structure in the electrical double layer at the ionic liquid| gold interface
to the steps of the electrode potential has been studied using surface plasmon resonance …

Potential-dependent structure of the ionic layer at the electrode interface of an ionic liquid probed using neutron reflectometry

N Nishi, J Uchiyashiki, Y Ikeda, S Katakura… - The Journal of …, 2019 - ACS Publications
Neutron reflectometry (NR) has been performed at the electrochemical interface between a
Nb film and an ionic liquid, trihexyltetradecylphosphonium tetrakis (pentafluorophenyl) …

Differential Capacitance of Ionic Liquid Confined between Metallic Interfaces

S Ntim, M Sulpizi - The Journal of Physical Chemistry B, 2024 - ACS Publications
We present here a detailed analysis of the electric double layer at the gold
electrode/[BMIM][BF4] interface using a polarizable model for the electrode, based on our …