The interpretation of XPS spectra: Insights into materials properties

PS Bagus, ES Ilton, CJ Nelin - Surface Science Reports, 2013 - Elsevier
We review basic and advanced concepts needed for the correct analysis of XPS features.
We place these concepts on rigorous foundations and explore their physical and chemical …

Core-level binding-energy shifts at surfaces and in solids

WF Egelhoff Jr - Surface Science Reports, 1987 - Elsevier
This review presents an overview of the theory and of various successful approaches to the
interpretation of core-level binding-energy shifts observed in photoelectron spectroscopy …

XPS determination of Mn oxidation states in Mn (hydr) oxides

ES Ilton, JE Post, PJ Heaney, FT Ling, SN Kerisit - Applied Surface Science, 2016 - Elsevier
Hydrous manganese oxides are an important class of minerals that help regulate the
geochemical redox cycle in near-surface environments and are also considered to be …

Main and satellite features in the Ni 2p XPS of NiO

PS Bagus, CJ Nelin, CR Brundle, BV Crist… - Inorganic …, 2022 - ACS Publications
The origin and assignment of the complex main and satellite X-ray photoelectron
spectroscopy (XPS) features of the cations in ionic compounds have been the subject of …

Combined multiplet theory and experiment for the Fe 2p and 3p XPS of FeO and Fe2O3

PS Bagus, CJ Nelin, CR Brundle, BV Crist… - The Journal of …, 2021 - pubs.aip.org
The Al K alpha, 1486.6 eV, based x-ray photoelectron spectroscopy (XPS) of Fe 2p and Fe
3p for Fe (III) in Fe 2 O 3 and Fe (II) in FeO is compared with theoretical predictions based on …

Natural widths of atomic K and L levels, Kα X‐ray lines and several KLL Auger lines

MO Krause, JH Oliver - Journal of Physical and Chemical Reference …, 1979 - pubs.aip.org
Semi‐empirical values of the natural widths of K, L 1, L 2, and L 3 levels, K α1 and K α2 x‐
ray lines, and KL 1 L 1, KL 1 L 2 and KL 2 L 3 Auger lines for the elements 10? Z? 110 are …

[LLIBRE][B] Core level spectroscopy of solids

F De Groot, A Kotani - 2008 - taylorfrancis.com
Core level spectroscopy has become a powerful tool in the study of electronic states in
solids. From fundamental aspects to the most recent developments, Core Level …

Interpretation of the x-ray photoemission spectra of cobalt oxides and cobalt oxide surfaces

TJ Chuang, CR Brundle, DW Rice - Surface Science, 1976 - Elsevier
CoO and Co3O4 have been studied by high-resolution X-ray photoemission. The
characteristic binding energies in the Co 2p3 2, 2p1 2, and 3s regions, their band shapes …

Mn exchange splitting in mixed-valence manganites

VR Galakhov, M Demeter, S Bartkowski, M Neumann… - Physical Review B, 2002 - APS
We present Mn 3 s x-ray photoelectron spectra of manganese oxides with the Mn formal
valency from 2+ to 4+. We found that the Sr 2+ do** or cation deficiency in manganites do …

Calculation of multiplet structure of core -vacancy levels

RP Gupta, SK Sen - Physical Review B, 1974 - APS
The multiplet splittings of core p-vacancy levels have recently been observed in various
transition-metal complexes and in some rare-earth as well as actinide complexes. This …