Towards sustainable metal-mediated ammonia electrosynthesis

S Li, X Fu, JK Nørskov, I Chorkendorff - Nature Energy, 2024 - nature.com
Ammonia is a key component of fertilizers, a crucial industrial chemical and a carbon-free
fuel. Electrosynthesis of ammonia from nitrogen under ambient conditions presents an …

Electrocatalytic nitrogen cycle: mechanism, materials, and momentum

L Li, L Xu, H Wang, H Wei, C Tang, G Li… - Energy & …, 2024 - pubs.rsc.org
Artificial nitrogen fixation has been pivotal in escalating agricultural productivity and
sustaining exponential human population growth. Nonetheless, these practices have …

Effect of lithium salt on lithium-mediated ammonia synthesis

X Fu, S Li, NH Deissler, JBV Mygind… - ACS Energy …, 2024 - ACS Publications
Recently, the lithium-mediated nitrogen reduction reaction (Li-NRR) has emerged as a
promising approach for electrochemical ammonia synthesis, facilitating more localized …

Localized High‐Concentration Electrolyte in Li‐Mediated Nitrogen Reduction for Ammonia Synthesis

H Yun, C Lim, M Kwon, D Lee, Y Yun… - Advanced …, 2024 - Wiley Online Library
The lithium‐mediated nitrogen reduction reaction (Li‐NRR) is a promising green alternative
to the Haber–Bosch process for ammonia synthesis. The solid electrolyte interphase (SEI) is …

Electron Sponge Effect by Dynamic-Regulated Electron Self-Flow toward Coupled Electrochemical Ammonia Synthesis

JJ Mu, XW Gao, Z Zhao, ZM Liu, Q Gu, WB Luo - ACS nano, 2024 - ACS Publications
A dynamic-regulated Pd–Fe–N electrocatalyst was effectively constructed with electron-
donating and back-donating effects, which serves as an efficient engineering strategy to …

[HTML][HTML] Lithium-mediated nitrogen reduction for electrochemical ammonia synthesis: From batch to flow reactor

X Fu - Materials Today Catalysis, 2023 - Elsevier
The electrochemical synthesis of ammonia has emerged as a sustainable alternative to the
traditional Haber-Bosch process. This review provides a comprehensive examination of the …

Bismuth-doped manganese molybdenum bimetallic oxide nanorods as a highly efficient nitrogen reduction catalyst

H Yin, Z Song, X **ng, L Miao, Y Lv, L Gan… - Materials Chemistry …, 2024 - pubs.rsc.org
Manganese molybdate has been shown to be an excellent NRR catalyst due to its uniform
rod-like structure and large specific surface area, and in order to further improve its catalytic …

General corrosion endowed by electrolyte engineering enhancing Lithium-Mediated nitrogen fixation

H Liu, Z Wang, H Ji, T Qian, C Yan, J Lu - Chemical Engineering Journal, 2024 - Elsevier
Lithium-mediated ammonia electrochemical synthesis (LMAES) holds promise for
approximating and superseding the capacity of Haber-Bosch technology. However, currently …

Steric Hindrance-Derived Li+ Solvation to Enhance Lithium-Mediated Nitrogen Reduction

Y Han, C Lim, Y Kim, H Baek, S Jeon, JW Han… - ACS Energy …, 2024 - ACS Publications
This study proposes a steric hindrance-derived electrolyte (STE) to generate Li+ anion-rich
solvation structures to enhance the Li-mediated nitrogen reduction reaction (Li-NRR), a …

Enhancing Ammonia Production by Ag Incorporation in Li-Mediated Nitrogen Reduction Reactions

Y Jeon, D Shin, K Yong, YJ Hwang - ACS Energy Letters, 2024 - ACS Publications
Conventional ammonia production relies on the Haber–Bosch process, which is an energy-
intensive process and emits significant amounts of CO2. Recent advances in …