Moving beyond 99.9% Coulombic efficiency for lithium anodes in liquid electrolytes

GM Hobold, J Lopez, R Guo, N Minafra, A Banerjee… - Nature Energy, 2021 - nature.com
As Li-ion battery costs decrease, energy density and thus driving range remains a roadblock
for mass-market vehicle electrification. While Li-metal anodes help achieve Department of …

Stabilizing metal battery anodes through the design of solid electrolyte interphases

Q Zhao, S Stalin, LA Archer - Joule, 2021 - cell.com
The solid electrolyte interphase (SEI) is a chemically distinct material phase formed by a
combination of electrochemical reduction and chemical reactions at both the explicit and …

Strategies towards enabling lithium metal in batteries: interphases and electrodes

B Horstmann, J Shi, R Amine, M Werres, X He… - Energy & …, 2021 - pubs.rsc.org
Despite the continuous increase in capacity, lithium-ion intercalation batteries are
approaching their performance limits. As a result, research is intensifying on next-generation …

Toward bottom-up understanding of transport in concentrated battery electrolytes

A Mistry, Z Yu, BL Peters, C Fang, R Wang… - ACS central …, 2022 - ACS Publications
Bottom-up understanding of transport describes how molecular changes alter species
concentrations and electrolyte voltage drops in operating batteries. Such an understanding …

Designing F/P Hybrid Polymer as Ultrastable Cationic Shielding Interphase for High‐Performance Lithium Metal Batteries

S Han, B Wu, H Wang, P Wen, L Zhang… - Angewandte Chemie …, 2023 - Wiley Online Library
Dendrite growth on electrode‐electrolyte interphase has severely limited applications of
lithium metal batteries (LMBs). Here, we developed an ionic alternating polymer with …

Smart construction of multifunctional Li1. 5Al0. 5Ge1. 5 (PO4) 3| Li intermediate interfaces for solid-state batteries

J Yu, Q Liu, X Hu, S Wang, J Wu, B Liang, C Han… - Energy Storage …, 2022 - Elsevier
Due to high ionic conductivity, low cost and excellent air stability, NASICON-type Li 1.5 Al
0.5 Ge 1.5 (PO) 4 (LAGP) electrolyte has been a promising candidate for high-performance …

A cation-tethered flowable polymeric interface for enabling stable deposition of metallic lithium

Z Huang, S Choudhury, H Gong, Y Cui… - Journal of the American …, 2020 - ACS Publications
A fundamental challenge, shared across many energy storage devices, is the complexity of
electrochemistry at the electrode–electrolyte interfaces that impacts the Coulombic …

Ultrathin zwitterionic polymeric interphases for stable lithium metal anodes

S Stalin, P Chen, G Li, Y Deng, Z Rouse, Y Cheng… - Matter, 2021 - cell.com
Lithium metal electrodeposits in the form of irregular morphological features, loosely termed
dendrites, on planar anode substrates. The deposits may lead to rapid battery failure and …

Functional polymers in electrolyte optimization and interphase design for lithium metal anodes

C Zhang, T **, G Cheng, S Yuan, Z Sun… - Journal of Materials …, 2021 - pubs.rsc.org
The lithium metal anode (LMA) is considered one of the most promising anode materials
because of its highest specific capacity and lowest reduction potential. However, the …

Ion States Impact Charge Transport and Dielectric Constant for Poly (ethylene oxide)-Based Sulfonylimide Lithium Ionomers

W Mei, D Yu, LA Madsen, RJ Hickey, RH Colby - Macromolecules, 2023 - ACS Publications
Understanding dielectric response and charge transport in ion-containing polymers is
essential for the design and implementation of these materials in energy-related …