Molecular Catalysis of Energy Relevance in Metal–Organic Frameworks: From Higher Coordination Sphere to System Effects
The modularity and synthetic flexibility of metal–organic frameworks (MOFs) have provoked
analogies with enzymes, and even the term MOFzymes has been coined. In this review, we …
analogies with enzymes, and even the term MOFzymes has been coined. In this review, we …
Analysis of electrocatalytic metal-organic frameworks
The electrochemical analysis of molecular catalysts for the conversion of bulk feedstocks
into energy-rich clean fuels has seen dramatic advances in the last decade. More recently …
into energy-rich clean fuels has seen dramatic advances in the last decade. More recently …
Electrocatalytic hydrogen evolution from a cobaloxime-based metal–organic framework thin film
Molecular hydrogen evolution catalysts (HECs) are synthetically tunable and often exhibit
high activity, but they are also hampered by stability concerns and practical limitations …
high activity, but they are also hampered by stability concerns and practical limitations …
Development of a UiO-type thin film electrocatalysis platform with redox-active linkers
Metal–organic frameworks (MOFs) as electrocatalysis scaffolds are appealing due to the
large concentration of catalytic units that can be assembled in three dimensions. To harness …
large concentration of catalytic units that can be assembled in three dimensions. To harness …
Mimicking the electron transport chain and active site of [FeFe] hydrogenases in one metal–organic framework: factors that influence charge transport
[FeFe] hydrogenase (H2ase) enzymes are effective proton reduction catalysts capable of
forming molecular dihydrogen with a high turnover frequency at low overpotential. The …
forming molecular dihydrogen with a high turnover frequency at low overpotential. The …
A 2, 2′-bipyridine-containing covalent organic framework bearing rhenium (I) tricarbonyl moieties for CO 2 reduction
DA Popov, JM Luna, NM Orchanian, R Haiges… - Dalton …, 2018 - pubs.rsc.org
The reduction of CO2 into higher energy products such as carbon-based fuels and
feedstocks is an attractive strategy for mitigating the continuous rise in CO2 emissions …
feedstocks is an attractive strategy for mitigating the continuous rise in CO2 emissions …
The odyssey of cobaloximes for catalytic H 2 production and their recent revival with enzyme-inspired design
Cobaloxime complexes gained attention for their intrinsic ability of catalytic H2 production
despite their initial emergence as a vitamin B12 model. The simple, robust, and synthetically …
despite their initial emergence as a vitamin B12 model. The simple, robust, and synthetically …
Heterogenization of a [NiFe] hydrogenase mimic through simple and efficient encapsulation into a mesoporous MOF
D Balestri, Y Roux, M Mattarozzi, C Mucchino… - Inorganic …, 2017 - ACS Publications
In the quest for new, efficient, and noble-metal-free H2-evolution catalysts, hydrogenase
enzymes are a source of inspiration. Here, we describe the development of a new hybrid …
enzymes are a source of inspiration. Here, we describe the development of a new hybrid …
Electrocatalytic water oxidation from a mixed linker MOF based on NU-1000 with an integrated ruthenium-based metallo-linker
A Howe, T Liseev, M Gil-Sepulcre… - Materials …, 2022 - pubs.rsc.org
A novel tetratopic metallo-linker,[Ru (tda)(py (PhCOOH) 2) 2], 1,(tda= 2, 2′: 6′, 2′′-
terpyridine-6, 6′′-dicarboxylate; py (PhCOOH) 2=(4, 4′-(pyridine-3, 5-diyl) dibenzoic …
terpyridine-6, 6′′-dicarboxylate; py (PhCOOH) 2=(4, 4′-(pyridine-3, 5-diyl) dibenzoic …
Electroactive Ferrocene at or near the Surface of Metal–Organic Framework UiO-66
Here, we describe the installation of a ferrocene derivative on and within the archetypal
metal–organic framework (MOF), UiO-66, by solvent-assisted ligand incorporation. Thin films …
metal–organic framework (MOF), UiO-66, by solvent-assisted ligand incorporation. Thin films …