Carboxylic acids have gained more and more importance as versatile and renewable
starting materials for the formation of platform molecules or high-value chemicals. Many …

This review highlights the preparation of sodium sulfinates (RSO2Na) and their multifaceted
synthetic applications. Substantial progress has been made over the last decade in the …

Development of the methodology for the preparation of vinyl sulfones is of significant interest
to organic chemists. Recently, numerous useful methods have been developed, mainly …

Oxidative coupling methodology is widely applied for the formation of carbon‐carbon and
carbon‐heteroatom bonds. This review focuses on methods for oxidative sulfonylation of …

Alkyl‐and aryl vinyl sulfones were obtained by eosin Y (EY)‐mediated visible‐light
photooxidation of sulfinate salts and the reaction of the resulting S‐centered radicals with …

An efficient radical addition/elimination reaction that enables selective incorporation of
alkenyl, alkynyl and allyl functional groups into the C (sp3)–H bond under green reaction …

A stereospecific decarboxylative silylation of acrylic and propiolic acids with silanes was
developed. This reaction represents the first example of decarboxylative C Si bond …

The BF3· OEt2-mediated disproportionate coupling reaction of sodium sulfinates was found
for the first time. In this reaction, various S–S (O) 2 bonds can be formed, efficiently giving …

A regioselective formation of C–S bonds has been achieved using a cross dehydrogenative
coupling (CDC) protocol using iodine as a catalyst and dimethyl sulfoxide as an oxidant …

A facile I2O5-mediated direct oxidative coupling of aromatic alkenes with thiols toward vinyl
sulfones has been developed under metal-free conditions. This methodology provides a …